Spectroscopic studies of jet-cooled AINi

Update item information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Behm, Jane M.; Arrington, Caleb A.
Title Spectroscopic studies of jet-cooled AINi
Date 1993
Description Resonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the presence of discrete transitions has allowed several bands to be rotationally resolved. From the analysis of these bands the ground state has been determined as X 2?5/2, originating from the 3SA3&Nio2 configuration, and the bond length has been measured as 2.3211?0.0007 A. The dissociation energy and ionization potential of AlNi have also been determined as D0( AlNi) =2.29?0.05 eV and I.P. ( AlNi) =6.95?0.09 eV, respectively.
Type Text
Publisher American Institute of Physics (AIP)
Volume 99
Issue 9
First Page 6409
Last Page 6415
DOI 10.1063/1.465879.
Language eng
Bibliographic Citation Behm, J. M., Arrington, C. A., & Morse, M. D. (1993). Spectroscopic studies of jet-cooled AINi. Journal of Chemical Physics, 99(9), 6409-15.
Rights Management ¬©American Institute of Physics. The following article appeared in Behm, J. M., Arrington, C. A., & Morse, M. D. (1993). Spectroscopic studies of jet-cooled AINi. Journal of Chemical Physics, 99(9), 6409-15. and may be found at http://dx.doi.org/10.1063/1.465879.).
Format Medium application/pdf
Format Extent 848,267 bytes
Identifier ir-main,16943
ARK ark:/87278/s6wd4hqv
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 703163
Reference URL https://collections.lib.utah.edu/ark:/87278/s6wd4hqv
Back to Search Results