OCR Text |
Show Table' ELEMENTARY REACTIONS uSED TO MODEL THE OXIDATION OF CH~ AND CO ... - - ---- CH20+M=HCO+H+M (W&D> CO+OH=C02+H (W~D) CO+H02=C02+0H (W&D> CH20+0H=HCO+H20 (W&D) CH20+H=HCO+H2 (W&D) CH20+0=HCO+OH (W&D) CH20+H02=HCO+H202 (W&D) HCO+M=H+CO+M HCO+02=CO+H02 HCO+OH=CO+H20 HCO+H=CO+H2 HCO+O=CO+OH (W&D) (W&D) (W&D) (W&D) (W&D) CH~+M=CH3+H+M (W&D) CH~+02=CH3+H02 (W&D) CH~+H=CH3+H2 (W&D) CH~+OH=CH3+H20 (W&D) CH~+O=CH3+0H (W&D> CH~+H02=CH3+H202 (W&D) CH3+02=CH30+0 (W&D) CH3+0=CH20+H (W&D) CH3+0H=CH20+H2 (W&D) CH3+0H=CH30+H (W&D) CH3~CH20=CH~+HCO (W&D) CH3+HCO=CH4+CO (W&D) CH3+H02=CH30+0H (W&D) CH30+M=CH20+H+M (W&D) CH30+02=CH20+H02 (W&D) CH30+H=CH20+H2 CH3+CH3=C2H6 CH3+CH3=C2H5+H CH3+CH3=C2H4+H2 C2H6+0=C2H5+0H C2H6+0H=C2H5+H20 C2H5+M=C2H4+H+M C2H5+02=C2H4+H02 C2H~+M=C2H3+H+M C2H~+0=CH3+HCO C2H4+0H=C2H3+H20 C2H3+02=HCO+CH20 S02+0+M=S03+M 503+0=502+02 CH3+HCL=CH3CL+H CH4+CL=CH3+HCL (l.J&D) (W&D) (W&D) (W&D) (W&D) (W&D) (W&D) (Wl.D) (W&D) (Tl.H) (TSANGl.HAMPSON) (PARK CPL469,84) (SMITH,CST241,83) (SMJTH,CST2~1 ,83) (Wl.D,PECS,8~) (Wl-D,PECS,8~) NO+H02=N02+0H N02+H=NO+OH N02+0=NO+02 N02+M=NO+0+11 H2+02=20H (LEU,JCP,1662,79) (DEAN, 19THINTCOM) (DEAN,19THINTCOM) (DEAN,19THINTCOM) (SLACK = 1. OE 1 3 ) OH+H2=H20+H (D-L~W) H+02=OH+0 (JAM,JCP 1981) 0+H2=OH+H (LEEDS) H+02+M=H02+M (SLACK) H20/2l./ H2/3.~1 02/1 .S/N2/0.01 H+02+N2=H02+N2 ,( SLACK = 3. 9E 19) 18 3.3E16 1 . 5E~ ' 7 5.75E13 7.6E12 3.3El~ 5.01E13 1. OE 12 1 • ~E 1 ~ 3.3E12 1 • OE 1 ~ 2.0E14 1 . OE 14 2.0E17 7.9E13 2.2E+4 3.5E+3 1 .2E+7 2.0E13 4.8E13 1. 3E 1 ~ ~.OEI2 2.0E16 1 .OE 10 3.0Ell 2.0E13 5.0E13 1. OE 12 2.0E13 1 • OOE 1 3 7.9~EI4 1 . OOE 16 2.51E13 8.70E+9 2.00E15 1 . OOE 12 6.30E18 1.32E+8 1 . 56E+~ 6.0E12 3.71E28 t..4E11 3 .'.6E 1 ~ 2.57E13 3.38E12 3.5E14 1 .OE 13 1. IE 16 3.0E13 1.17E9 5. 13E 16 1. 8E 10 2. lL 1 G 3.9E19 0.0 1 .3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 3.0 3.08 2.08 0.0 0.0 0.0 0.0 0.0 0.5 0.5 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.05 0.0 0.0 61000. -0.77 22930. 170. 10500. ~600. 8000. 19000. 7000. O. O. O. 88000. 56000. 8750. 2000. 7630. 18000. 29000. 2000. O. 27~10. 6000. O. O. 21000. 6000. O. 0.0 26520. 32000. 6360. 1810. 30000. 5000. 0.0 108720. 1.55 430. 2.75 ~200. 0.0 O. -4.0 5265. 0.0 6100. 0.0 9000. 0.0 3850. 0.0 -200. 0.8 O. 0.0 o. 0.0 65935. 0.0 1.3000. 1 .3 3626. -0.816 16507. 1.0 0090. -1.0 0.0 - 1 .35 0.0 |