Removal of arsenate and arsenite by calcined nanocrystaline layered double hydroxides

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Publication Type thesis
School or College College of Mines & Earth Sciences
Department Metallurgical Engineering
Author Wahbah, Eman Rashad mihoub
Title Removal of arsenate and arsenite by calcined nanocrystaline layered double hydroxides
Date 2015-08
Description This work studies the removal of arsenic (V), arsenate, and arsenic (III), arsenite, from aqueous solution using calcined Quintinite-3T (Al/Mg mixed oxides) and calcined La-LDHs (La/Mg mixed oxides). The two adsorbents Quintinite-3T and La-LDHs were prepared, calcined at different temperatures, and characterized by XRD, BET, and SEM. The surface area of the calcined Quintinite-3T was 193.4 m2/g, while the surface area of the calcined La-LDHs was 112.4 m2/g. The particles size ranged from 12 to 56 nm for the uncalcined Quintinite-3T and from 24 to 42 nm for the calcined Quintinite-3T. The particle size ranged from 27 to 56 nm for as-synthesized La-LDHs and from 18 to 35 nm for the calcined La-LDHs. Also, new hybrid adsorbent was synthesized and characterized as well. Kinetic analysis, adsorption isotherm, and factors affecting the adsorption were investigated. Calcined Quintinite-3T retained As(v) and did not release it back to water even after an entire month. The adsorption of As(V) and As(III) by calcined La-LDHs increased with time up to 2 weeks and 1 month, respectively.
Type Text
Publisher University of Utah
Subject Arsenic; La-LDHs; Quintinite-3T; Water treatment
Dissertation Institution University of Utah
Dissertation Name Master of Science
Language eng
Rights Management Copyright © Eman Rashad mihoub Wahbah 2015
Format Medium application/pdf
Format Extent 26,910 bytes
Identifier etd3/id/3884
ARK ark:/87278/s6448vst
Setname ir_etd
ID 197435
Reference URL https://collections.lib.utah.edu/ark:/87278/s6448vst
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