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Show TABLE 2. Toluene and Iso-Octane Quasiglobal Kinetics Hodel GLOBAL HfCHAMSM Toluene (arr«T,at1c) C;Y 3.5 C?H2 * 0.5 H2 C7Hfl • 3.5 02- 7 CO • 4 H. C^H 4 OH -3.25 C£H2 • 0.5 CO • 0.5 ^ 0 * 0.75 H£ Iso-Octane (alIphatlc) C8H18- •4 C2H4 * H2 ceHie + 4 V CO * 9 H. C8H18 * 0 H "3-75 C2H4 + °"5 C 0 + °- 5 H2° * K 5 HZ Secondary Fuel C2H 4 6 OH - 4 H O •> 2 CO C2H2 4 2 OH-- 2 CO + 2 H? CH, • 6 OH--2 CO + 2 H,0 + H 2 4 c L C2H4 4 2 OH - 2 CO 4 3 H2 C2H2 4 02 = 2 CHO C,H. 4 H * C,H, 4 H, 4 M 2 4 Z ee Soot Reactions C7H8 HC --soot 1.7982 HO 4.4963 E9 1.4721 E17 1.0473 E12 1.2900 E9 2.0000 .El 7 4.7850 E15 2.8000 E16 2.2020 E15 2.1129 E27 4.0000 E12 2.0e93 E17 •4.0465 E14' 0 0 0 -3.0 0 0 -2.0 E/R 3.5000 E4 2.6785 E4 1.4510 E4 3.5229 E3 2.5160 E4 1.4919 E4 1.3563 E4 0 1.2079 E4 6.3062 E3 1.4092 E4 3.S810 E4 1.6110 E4 PO-TR DEPEfiDfNClES <C7H83 1.0 [C7HB)°-5C02),-° [C7H8],-°[0H]1-0 (ceHie] 1.0 [cflHlflr'-W-° [C2H2]'-°[OH]'-5 [C2H4],-°COH31-0 [C2H2]1-°[02]1-0 CC2H43,-°[H]1-° [HC]'-«W°-5 soot 4 0 2 - - C 0 2 [so'ot] = - 12 PQ At A 1 • H po. 1 • KT,'/ T KB0 P,0 . (1-X) K1 - A< exp {- E ^ R T } , i = A. B, T, Z I | 2.0000 El | 4.4600 E-3 | 1.5100 E5 I 2.1300 El 1.5090 E4 7.6490 E3 4.8520 E4 •2.0630 E3 As indicated by the equation for [soot] 7 3 where A • 6 (C /p • D ) (cm surface/cm ), P_ = partial pressure of 02 (atm), C • lg • soot/cra of gas), p « (g • soot/cm of soot), 0 • dia~eter of soot (cm), [soot] * mass of soot/volun-* of gas (g/cm ). sign on A Indicates rate of fcrratlon of soot 1.2.12 |