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Show Glarborg, P., Dam-Johansen, K and Kristensen, P.G. (1993) Report to GRI, Contract No. 5091-260- 2126. GRI-Mech Version 1.1 (1994) CRV AX. SRI. COM, released 3/15/1994. Kee, R.J., Rupley, F.M. and Miller, J.A. (1989) Sandia Nat. Lab. Report No. SAND89-8009. Kobayashi, H. (1977) Removal of Nitrogen Oxides with Aqueous Solutions of Inorganic and Organic Reagents. Envir. Sci. Technol., 11, No.2, 190-192. Kyllonen, D.M. (1970) Method for Removing N02 from Waste Gases. U.S, Patent 3,498,743. Lee, Y.J., Markussen, J.M. and Pennline, H.W. (1989) Enhancement of SOiN02 removal via Hot Radical Reactions, DOE Report, Pittsburgh Energy Technology Center, Pittsburgh, PA. Lutz, A.E., Kee, R.J., and Miller, J.A. (1991) Sandia Nat. Lab. Report No. SAND87-8248. Lyon, R.K, Cole, J.A., Kramlich, J.C. and Chen, S.L. (1990) The Selective Reduction of S03 to S02 and the Oxidation of NO to N02 by Methanol. Comb. Flanle, 81, 30-39. Miller, J.A. and Bowman, C.T. (1989) Mechanism and Modeling of Nitrogen Chemistry in Combustion. Progr. Energy Combust. Sci., 15, 287-338. NIST Chemical Kinetic Database (1994) Version 6. O'Dowd, W.J., Markussen, J.M., Pennline, H.W. and Resnik, K.P. (1994) Characterization of N02 and S02 Removals in a Spray Dryer/Baghouse System, Ind. Eng. Chem. Res., 33, 2749- 2756. Pont, J.N., Evans, A.B., England, G.C., Lyon, R.K. and Seeker, W.R. (1993) Evaluation of the CombiNOx Process at Pilot Scale, Environ. Progress, 12, 140-145. Senjo, T. and Kobayashi, M. (1977) Process for Removing Nitrogen Oxides from Waste Gas. U.S. Patent 4,029,739. Shojaie, R., Markussen, J.M. and Pennline, H.W. (1992) A Novel Approach for SO/NOx Control Using Ultrasound. AIChE Spring National Meeting, New Orleans, LA, paper 99b. Zamansky, V.M., Lyon, R.K., Evans, A.B., Pont, J.N., Seeker, W.R. and Schmidt, C.E. (1993) Development of Process to Simultaneously Scrub N02 and S02 from Coal-Fired Flue Gas, 1993 S02 Control Symposium, EPRI/EPA/DOE, Boston, MA, VoL 3, Session 7. Zamansky, V.M., Ho, L., Maly, P. and Seeker, W.R. (1995) Hydrogen Peroxide Injection - A Novel Technology for Multiple Air Pollutant Emissions Removal, 3d Intern. Conf. on Combustion Technologies for a Clean Environment, Lisbon, Portugal, Vol. 2, pp. 26.4 (24-32). FIGURE CAPTIONS Figure 1. Boiler Simulator Facility (BSF) schematic. Figure 2. Performance of NO removal during natural gas fIring for injection of H20 2, CH30H and their mixture at 1: 1 molar ratio; a - effect of temperature, b - effect of NO initial concentration, c - effect of the additive/NO molar ratio, d - effect of oxygen concentration. Figure 3. NO remaining during natural gas and coal firing. a - coal firing with injection of the three additives at different temperatures, b - variation of S02 doping during natural gas fIring with sampling at two locations (CH30H injected at 894 K), c - influence of S02 and ash during natural gas and coal firing (CH30H injected at 866 K), d - effect of quench rate on NO conversion and reconversion during coal fIring (CH30H injected at 866 K). 18 . |