| Publication Type | pre-print |
| School or College | College of Engineering |
| Department | Materials Science & Engineering |
| Creator | Scarpulla, Michael |
| Other Author | Kosyak, V.; Karmarkar, M. A. |
| Title | Temperature dependent conductivity of polycrystalline Cu 2ZnSnS 4 thin films |
| Date | 2012-01-01 |
| Description | The temperature-dependent conductivity of Cu2ZnSnS4 (CZTS) thin films prepared by sulfurization of different sputtered ZnS/Cu/Sn stacks and also of the same stack annealed for different times was investigated from 30-300 K. Fitting of the through-thickness conductivity requires a model including Mott variable-range hopping (M-VRH), nearest-neighbor hopping (NNH), and thermionic emission over grain boundary (GB) barriers. The GB barrier height varies sensitively from 50-150 (65) meV with annealing and especially with [Cu]/([Zn]þ[Sn]) ratio but is independent of [Zn]/[Sn] ratio. These results are critical for understanding the behavior of solar cells based on polycrystalline CZTS absorber layers. |
| Type | Text |
| Publisher | American Institute of Physics (AIP) |
| Volume | 100 |
| Issue | 26 |
| Dissertation Institution | University of Utah |
| Language | eng |
| Bibliographic Citation | Kosyak, V., Karmarkar, M. A., & Scarpulla, M. A. (2012). Temperature dependent conductivity of polycrystalline Cu 2ZnSnS 4 thin films. Applied Physics Letters, 100(26), no. 263903. |
| Rights Management | ©American Institute of Physics. The following article appeared in Kosyak, V., Karmarkar, M. A., & Scarpulla, M. A. Applied Physics Letters, 100 |
| Format Medium | application/pdf |
| Format Extent | 517,835 bytes |
| Identifier | uspace,17651 |
| ARK | ark:/87278/s6vt29v7 |
| Setname | ir_uspace |
| ID | 708067 |
| Reference URL | https://collections.lib.utah.edu/ark:/87278/s6vt29v7 |