| Publication Type |
journal article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Miller, Joel Steven |
| Other Author |
Novoa, Juan J.; Lafuente, Pilar; Del Sesto, Rico E. |
| Title |
On the existence of long C-C bonds between pairs of anions which repel: when and why? A test case on the [TCNE]22- dimers found in ionic crystals* |
| Date |
2002 |
| Description |
Many of the Cm[TCNE]n (C = cation) salts have intradimer C-C interactions in the range of 2.9 to 3.5 A(°) and show the electronic fingerprints associated with C-C bond formation (IR and UV spectra, magnetic properties, structural changes), despite the fact that two [TCNE].- anions should repel each other due to purely Coulombic considerations. Herein, we analyze these pairwise interactions in detail for a particular crystal in which such a C-C bond is found, to understand when and why these bonds are formed in a general case. |
| Type |
Text |
| Publisher |
Royal Society of Chemistry |
| Volume |
4 |
| Issue |
65 |
| First Page |
373 |
| Last Page |
377 |
| Subject |
Electron; Spectroscopic; Salts |
| Language |
eng |
| Bibliographic Citation |
Novoa, J. J., Lafuente, P., Del Sesto, R. E., & Miller, J. S. (2002). On the existence of long C-C bonds between pairs of anions which repel: when and why? A test case on the [TCNE]22- dimers found in ionic crystals. CrystEngComm, 4(65), 373-7. |
| Rights Management |
©Royal Society of Chemistry |
| Format Medium |
application/pdf |
| Format Extent |
302,012 bytes |
| Identifier |
ir-main,5571 |
| ARK |
ark:/87278/s6z32h23 |
| Setname |
ir_uspace |
| ID |
704939 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6z32h23 |
