Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Morse, Michael David |
Other Author |
Russon, Larry M.; Heidecke, Scott A.; Birke, Michelle K.; Armentrout, P. B. |
Title |
Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+ |
Date |
1993 |
Description |
The bond dissociation energies of Ti2+, V+2 , Co+2, and Co: have been measured from the sudden onset of predissociation in the photodissociation spectra of these molecules, yielding values of D?(Ti+2)=2.435+0.002 eV, D?(V+2)=3.140?0.002 eV, D?(Co+2)=2.7651?0.001 eV, and D?(Co+3)=2.086?0.002 eV. These values are in good agreement with values previously determined from collision-induced dissociation experiments. General criteria for the interpretation of predissociation thresholds as bond dissociation energies and periodic trends in the bonding of the 3d transition metal diatomic neutrals and monocations are discussed. |
Type |
Text |
Publisher |
American Institute of Physics (AIP) |
Volume |
100 |
Issue |
7 |
First Page |
4747 |
Last Page |
4755 |
DOI |
10.1063/1.466265 |
Language |
eng |
Bibliographic Citation |
Russon, L. M., Heidecke, S. A., Birke, M. K., Morse, M. D., & Armentrout, P. B. (1993). Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+. Journal of Chemical Physics, 100(7), 4747-55. |
Rights Management |
©American Institute of Physics. The following article appeared in Russon, L. M., Heidecke, S. A., Birke, M. K., Morse, M. D., & Armentrout, P. B. (1993). Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+. Journal of Chemical Physics, 100(7), 4747-55. and may be found at http://dx.doi.org/10.1063/1.466265. |
Format Medium |
application/pdf |
Format Extent |
1,117,131 bytes |
Identifier |
ir-main,16945 |
ARK |
ark:/87278/s6rj536p |
Setname |
ir_uspace |
ID |
707426 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6rj536p |