Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Morse, Michael David |
Other Author |
Fabbi, Jacqueline C.; Karlsson, Lars; Langenberg, Jon. D.; Costello, Quinton D. |
Title |
Dispersed fluorsecence spectroscopy of AINi, NiAu, and PtCu |
Date |
2003 |
Description |
Dispersed fluorescence studies of AlNi, NiAu, and PtCu have been performed, providing spectroscopic information about the ground and low-lying excited electronic states. Vibrational frequencies are reported for the ground X 2?5/2 state of all three molecules. In the case of AlNi, fluorescence to all five of the states originating from the 3dNi 9 3sAl2?2 manifold has been observed. For both NiAu and PtCu, fluorescence to two low-lying excited states in addition to the ground state was observed. Relative energies, vibrational constants, and, when possible, V values of these states are reported. Comparisons of the measured electronic states to the predictions of a ligand-field plus spin?orbit model are also provided, along with a comparison of the electronic structure of PtCu to that of PtH. |
Type |
Text |
Publisher |
American Institute of Physics (AIP) |
Volume |
118 |
Issue |
20 |
First Page |
9247 |
Last Page |
9258 |
DOI |
10.1063/1.1567712 |
Language |
eng |
Bibliographic Citation |
Fabbi, J. C., Karlsson, L., Langenberg, J. D., Costello, Q. D., & Morse, M. D. (2003). Dispersed fluorsecence spectroscopy of AINi, NiAu, and PtCu. Journal of Chemical Physics, 118(20), 9247-58. |
Rights Management |
©American Institute of Physics. The following article appeared in Fabbi, J. C., Karlsson, L., Langenberg, J. D., Costello, Q. D., & Morse, M. D. (2003). Dispersed fluorsecence spectroscopy of AINi, NiAu, and PtCu. Journal of Chemical Physics, 118(20), 9247-58 and may be found at DOI: 10.1063/1.1567712. |
Format Medium |
application/pdf |
Format Extent |
139,228 bytes |
Identifier |
ir-main,16932 |
ARK |
ark:/87278/s68w3xr4 |
Setname |
ir_uspace |
ID |
705796 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s68w3xr4 |