Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Physics |
Creator |
Vardeny, Zeev Valentine |
Other Author |
Orenstein, Joseph; Baker, G. L. |
Title |
Photoinduced infrared activity in polyacetylene |
Date |
1983-06 |
Description |
Photoexcitation of trans - but not cis -polyacetylene, results in the appearance of strongly-ir-active local modes at 1370 and 1260 cm-1. This observation demonstrates that the photogeneration of self-localized charge carriers is unique to the trans isomer. In spite of their localization the kinetic mass of these photocarriers is small, Mc ≈ (1-2.5)m, a result which is in quantitative agreement with calculations based on single-chain models. |
Type |
Text |
Publisher |
American Physical Society |
Journal Title |
Physical Review Letters |
Volume |
50 |
Issue |
25 |
First Page |
2032 |
Last Page |
2035 |
DOI |
10.1103/PhysRevLett.50.2032 |
citatation_issn |
0031-9007 |
Subject |
Photoinduced infrared activity; Photoexcitation |
Subject LCSH |
Polyacetylenes -- Optical properties |
Language |
eng |
Bibliographic Citation |
Vardeny, Z., Orenstein, J., & Baker, G. L. (1983). Photoinduced infrared activity in polyacetylene. Physical Reveiw Letters, 50(25), June, 2032-5. |
Rights Management |
(c) American Physical Society http://dx.doi.org/10.1103/PhysRevLett.50.2032 |
Format Medium |
application/pdf |
Format Extent |
360,673 bytes |
Identifier |
ir-main,9573 |
ARK |
ark:/87278/s6mc9hjp |
Setname |
ir_uspace |
ID |
706163 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6mc9hjp |