Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Morse, Michael David |
Other Author |
Heidecke, Scott A.; Fu, Zhenwen; Colt, John R. |
Title |
Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit |
Date |
1992 |
Description |
Spectra of jet-cooled AlAr and AlKr have been collected over the range from 31 000 cm -? to the ionization limit, using the technique of resonant two-photon ionization spectroscopy with mass spectrometric detection. Adiabatic ionization potentials have been accurately measured for both molecules, and have been estimated for AlAr? and AlAr?. The spin-orbit splittings in the X ?II ground state have been determined for both AlAr and AlKr, and ground-state bond strengths have been accurately measured as Do [AlAr, Xi ?II1/2 (3p)] = 122.4 ? 4 cm-? and D?[27A1 84Kr, X, ?II1/2 (3p)] = 194.7 ? 0.8 cm-? . These values have also been combined with the measured ionization potentials to derive D?(Al+-Ar) = 982.3 ? 5 cm-? and D?(Al+-Kr) = 1528.5 ? 2cm- ?. |
Type |
Text |
Publisher |
American Institute of Physics (AIP) |
Volume |
97 |
Issue |
3 |
First Page |
1692 |
Last Page |
1710 |
DOI |
10.1063/1.463158 |
Language |
eng |
Bibliographic Citation |
Heidecke, S. A., Fu, Z., Colt, J. R., & Morse, M. D. (1992). Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit. Journal of Chemical Physics, 97(3), 1692-710. |
Rights Management |
©American Institute of Physics. The following article appeared in Heidecke, S. A., Fu, Z., Colt, J. R., & Morse, M. D. (1992). Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit. Journal of Chemical Physics, 97(3), 1692-710. and may be found at http://dx.doi.org/10.1063/1.463158. |
Format Medium |
application/pdf |
Format Extent |
2,564,648 bytes |
Identifier |
ir-main,16994 |
ARK |
ark:/87278/s6514gs1 |
Setname |
ir_uspace |
ID |
706594 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6514gs1 |