Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Miller, Joel Steven
Other Author Pokhodnya, Konstantin I.
Title Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF
Date 2007
Description The dissolution of Ni(COD)2 (COD = 1,5-cyclooctadiene) into dichloromethane leads to decomposition and formation of a room temperature magnetic material, whereas the reaction of Ni(COD)2 and tetracyanoethylene (TCNE) in THF forms paramagnetic materials including NiII[C4(CN)8](THF)2.xTHF. These results are discussed in context with a recent report of a room temperature magnet based upon the reaction of Ni(COD)2 and TCNE in dichloromethane.
Type Text
Publisher Royal Society of Chemistry
Volume 4
Issue CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF. Journal of Materials Chemistry, 17(34
First Page 3585
Last Page 3587
Subject Dinuclear complexes
Subject LCSH Iron compounds; Hysteresis; Ferromagnetism; Magnetic materials; Hydrogen bonding; Transition metal complexes; Ligands
Language eng
Bibliographic Citation Miller, J. S., & Pokhodnya, K. I. (2007). Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF. Journal of Materials Chemistry, 17(34), 3585-7.
Rights Management (c)Royal Society of Chemistry
Format Medium application/pdf
Format Extent 344,319 bytes
Identifier ir-main,7731
ARK ark:/87278/s63v01w4
Setname ir_uspace
ID 707431
Reference URL https://collections.lib.utah.edu/ark:/87278/s63v01w4
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