Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Miller, Joel Steven |
Other Author |
Pokhodnya, Konstantin I. |
Title |
Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF |
Date |
2007 |
Description |
The dissolution of Ni(COD)2 (COD = 1,5-cyclooctadiene) into dichloromethane leads to decomposition and formation of a room temperature magnetic material, whereas the reaction of Ni(COD)2 and tetracyanoethylene (TCNE) in THF forms paramagnetic materials including NiII[C4(CN)8](THF)2.xTHF. These results are discussed in context with a recent report of a room temperature magnet based upon the reaction of Ni(COD)2 and TCNE in dichloromethane. |
Type |
Text |
Publisher |
Royal Society of Chemistry |
Volume |
4 |
Issue |
CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF. Journal of Materials Chemistry, 17(34 |
First Page |
3585 |
Last Page |
3587 |
Subject |
Dinuclear complexes |
Subject LCSH |
Iron compounds; Hysteresis; Ferromagnetism; Magnetic materials; Hydrogen bonding; Transition metal complexes; Ligands |
Language |
eng |
Bibliographic Citation |
Miller, J. S., & Pokhodnya, K. I. (2007). Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF. Journal of Materials Chemistry, 17(34), 3585-7. |
Rights Management |
(c)Royal Society of Chemistry |
Format Medium |
application/pdf |
Format Extent |
344,319 bytes |
Identifier |
ir-main,7731 |
ARK |
ark:/87278/s63v01w4 |
Setname |
ir_uspace |
ID |
707431 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s63v01w4 |