| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Morse, Michael David |
| Other Author |
Behm, Jane M.; Arrington, Caleb A. |
| Title |
Spectroscopic studies of jet-cooled AINi |
| Date |
1993 |
| Description |
Resonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the presence of discrete transitions has allowed several bands to be rotationally resolved. From the analysis of these bands the ground state has been determined as X 2?5/2, originating from the 3SA3&Nio2 configuration, and the bond length has been measured as 2.3211?0.0007 A. The dissociation energy and ionization potential of AlNi have also been determined as D0( AlNi) =2.29?0.05 eV and I.P. ( AlNi) =6.95?0.09 eV, respectively. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Volume |
99 |
| Issue |
9 |
| First Page |
6409 |
| Last Page |
6415 |
| DOI |
10.1063/1.465879. |
| Language |
eng |
| Bibliographic Citation |
Behm, J. M., Arrington, C. A., & Morse, M. D. (1993). Spectroscopic studies of jet-cooled AINi. Journal of Chemical Physics, 99(9), 6409-15. |
| Rights Management |
©American Institute of Physics. The following article appeared in Behm, J. M., Arrington, C. A., & Morse, M. D. (1993). Spectroscopic studies of jet-cooled AINi. Journal of Chemical Physics, 99(9), 6409-15. and may be found at http://dx.doi.org/10.1063/1.465879.). |
| Format Medium |
application/pdf |
| Format Extent |
848,267 bytes |
| Identifier |
ir-main,16943 |
| ARK |
ark:/87278/s6wd4hqv |
| Setname |
ir_uspace |
| ID |
703163 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6wd4hqv |
