| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Miller, Joel Steven; Epstein, Arthur J. |
| Other Author |
Calabrese, Joseph C; Glatzhofer, Daniel T. |
| Title |
Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited) |
| Date |
1988 |
| Description |
A new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-l-oxy) butadiyne has been prepared and characterized by x-ray diffraction, infrared and Raman spectroscopies, and magnetic susceptibility. Unlike t h e Pccn-a phase, the B phase belongs to the Pca2y1 space group [a = 14.265(1) A(o),b = 8.079 (3) A(o), and c = 18.865(2) A(o), V = 2174.1 A(o) 3, Z = 4, T = - 100 °C, Ru = 4.8%, Rw = 5.0%) . The C=C, CC-CC, and NO distances are 1.201, 1.391, and 1.293 A., respectively. The only intermolecular interactions a r e 1.844-A(o)-OH... ON hydrogen bonding interactions. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Volume |
63 |
| Issue |
8 |
| First Page |
2949 |
| Last Page |
2951 |
| Subject |
Molecular; Magnetic; Thermal |
| Language |
eng |
| Bibliographic Citation |
Miller, J. S., Calabrese, J. C., Glatzhofer, D. T., & Epstein, A. J. (1988). Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited). Journal of Applied Physics, 63(8), 2949-51. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in (author, journal. issue, year) and may be found at (URL/link for published article abstract). |
| Format Medium |
application/pdf |
| Format Extent |
395,843 bytes |
| Identifier |
ir-main,5921 |
| ARK |
ark:/87278/s6c82tdr |
| Setname |
ir_uspace |
| ID |
702816 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6c82tdr |
