Studies in the cycloproparene series: cycloaddition reactions of diarylmethylidenecycloproparenes

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Stang, Peter J.
Other Author Halton, Brian; Kay, Andrew J.; McNichols, Aileen T.; Apeloig, Yitzhak; Boese, Roland; Maulitz, Andreas H.; Haumann, Thomas
Title Studies in the cycloproparene series: cycloaddition reactions of diarylmethylidenecycloproparenes
Date 2001
Description Diarylmethylidenecyclopropanaphthalenes 4b-d add diphenylisobenzofuran (DPIBF) and α-pyrone across the exocyclic double bond to give ring expanded products 11b-d and 13b-d that result from subsequent relief of ring strain in the non-isolable spirocyclic intermediates 10 and 12, respectively. The benzene homologues 3b and 3c add DPIBF across the bridge bond to give the norcaradiene adducts 19b and 19c.
Type Text
Publisher Arkat USA Inc.
Volume 2001
Issue 7
First Page 8
Last Page 31
Subject Cycloproparene series; Cycloaddition; Diarylmethylidenecycloproparenes; Ab initio calculations; Strained aromatics; Acetylenic-iodonium salts; Crystal structures; Cyclobutanes, Diels-Alder cycloaddition; norcaradienes
Subject LCSH Polymers; Molecular structure; Ring formation (Chemistry); Heterocyclic compounds; X-ray crystallography
Language eng
Bibliographic Citation Halton, B., Kay, A. J., McNichols, A. T., Stang, P. J., Apeloig, Y., Boese, R., Maulitz, A. H., & Haumann, T. (2001). Studies in the cycloproparene series: cycloaddition reactions of diarylmethylidenecycloproparenes. Arkivoc, 2001(7), 8-31.
Rights Management (c)Halton, B., Kay, A. J., McNichols, A. T., Stang, P. J., Apeloig, Y., Boese, R., Maulitz, A. H., & Haumann, T.
Format Medium application/pdf
Format Extent 267,921 bytes
Identifier ir-main,9020
ARK ark:/87278/s6nk3zcx
Setname ir_uspace
ID 704564
Reference URL https://collections.lib.utah.edu/ark:/87278/s6nk3zcx
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