Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Miller, Joel Steven
Other Author Min, Kil Sik
Title Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media
Date 2006
Description The reaction of (NBu4)3[VIII(ox)3] (1, ox = oxalate) and M(II) (M= Fe, Co, Ni, Cu) ions in MeCN, leads to the isolation of V-based coordination polymers of [N(n-Bu)4][FeIIVIII(ox)3]? 0.30{[N(n-Bu)4](BF4)} (2), [N(n-Bu)4][CoIIVIII(ox)3]?0.75{[N(n-Bu)4](BF4)} (3), [N(n-Bu)4][NiIIVIII(ox)3]?0.20{[N(n-Bu)4](BF4)}?0.20MeCN (4), and [N(n-Bu)4][CuIIVIII(ox)2](BF4)2 (5) composition.
Type Text
Publisher Royal Society of Chemistry
First Page 2463
Last Page 2467
Subject Magnetic; Coupling; Diffraction
Language eng
Bibliographic Citation Min, K. S., & Miller, J. S. (2006). Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media. Journal of the Chemical Society, Dalton, 2463-7.
Rights Management ©Royal Society of Chemistry
Format Medium application/pdf
Format Extent 269,540 bytes
Identifier ir-main,5663
ARK ark:/87278/s6ns1c7d
Setname ir_uspace
ID 704329
Reference URL https://collections.lib.utah.edu/ark:/87278/s6ns1c7d
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