Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Poulter, Charles Dale |
Other Author |
Woodside, Andrew B.; Huang, Zheng |
Title |
Trisammonium geranyl diphosphate |
Date |
1987 |
Description |
Geranyl chloride. To a flame-dried, 100-mL, three-necked, round-bottomed flask equipped with a magnetic stirrer, low temperature thermometer, rubber septum, and nitrogen inlet adapter, is added 1 .47 g (11 mmol) of N-chlorosuccinimide (Note 1) . The powder is dissolved in 45 mL of dry dichloromethane (Note 2), and the resulting solution is cooled to -30°C with a dry ice/acetonitrile bath. Freshly distilled dimethyl sulfide (0.87 mL, 0.74 g, 12 mmol) is added dropwise by syringe. The mixture is warmed to 0°C with an ice-water bath, maintained at that temperature for 5 min, and cooled to -40°C. To the resulting milky white suspension is added dropwise by syringe 1.54 g (10 mmol) of geraniol (Note 3) dissolved in 5 mL of dry dichlromethane. |
Type |
Text |
Publisher |
Organic Syntheses |
First Page |
211 |
Last Page |
219 |
Subject |
Buffer; Solution; Chloride |
Language |
eng |
Bibliographic Citation |
Woodside, A. B., Huang, Z., & Poulter, C. D., (1987). Trisammonium geranyl diphosphate. Organic Syntheses., 66, 211-9. |
Rights Management |
(c)Organic Syntheses |
Format Medium |
application/pdf |
Format Extent |
584,092 bytes |
Identifier |
ir-main,1888 |
ARK |
ark:/87278/s64q8c9m |
Setname |
ir_uspace |
ID |
704537 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s64q8c9m |