| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Citir, Murat; Liu, Fuyi |
| Title |
Methane activation by cobalt cluster cations, Con+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexes |
| Date |
2009 |
| Description |
The kinetic energy dependences of the reactions of Con + (n=2-16) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. The main products are hydride formation, ConD+, dehydrogenation to form ConCD2 +, and double dehydrogenation yielding ConC+. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
130 |
| Issue |
5 |
| First Page |
54309 |
| Last Page |
16 |
| DOI |
10.1063/1.3073886 |
| citatation_issn |
219606 |
| Subject |
Cobalt ions; Transition metal ions; Bond energies; Endothermic reactions; Dehydrogenation; Deuterated methane |
| Subject LCSH |
Thermochemistry; Excited state chemistry; Cobalt; Methane; Deuterium |
| Language |
eng |
| Bibliographic Citation |
Citir, M., Liu, F., & Armentrout, P. B. (2009). Methane activation by cobalt cluster cations, Con+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexes. Journal of Chemical Physics, 130(5), no. 054309. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Citir, M., Liu, F., & Armentrout, P. B., Journal of Chemical Physics, 130(5), 2009 and may be found at http://dx.doi.org/10.1063/1.3073886 |
| Format Medium |
application/pdf |
| Format Extent |
52,660 bytes |
| Identifier |
ir-main,7917 |
| ARK |
ark:/87278/s6jt07sz |
| Setname |
ir_uspace |
| ID |
704942 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6jt07sz |
