| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Miller, Joel Steven |
| Other Author |
Her, Jae- Hyuk; Stephens, Peter W.; Zhu, Qiuying; Nelson, Kendric J. |
| Title |
Structure of CrIIF(NCMe)2BF4. Rietveld refinement of a component of a physical mixture of unknown composition |
| Date |
2008 |
| Description |
The reaction of CrII(NCMe)4(BF4)2 and [NBun 4][TCNE] (TCNE ¼ tetracyanoethylene) in CH2Cl2 forms a solid that is a mixture of an amorphous reduced-TCNE containing phase(s) and a crystalline component. Rietveld refinement of the high-resolution, synchrotron X-ray powder pattern enabled the determination of the structure of the crystalline phase to be of CrIIF(NCMe)2BF4 composition and illustrates that this methodology can be used to determine the structure of a crystalline substance of unknown composition in the presence of confounding information from coexisting amorphous material. |
| Type |
Text |
| Publisher |
Royal Society of Chemistry |
| Volume |
10 |
| Issue |
12 |
| First Page |
1728 |
| Last Page |
1730 |
| Subject |
Organic-based magnets; Powder X-ray diffraction; Tetracyanoethylene |
| Subject LCSH |
Organic compounds -- Magnetic properties; Crystals -- Structure |
| Language |
eng |
| Bibliographic Citation |
Her, J.- H., Stephens, P. W., Zhu, Q., Nelson, K. J., & Miller, J. S. (2008). Structure of CrIIF(NCMe)2BF4. Rietveld refinement of a component of a physical mixture of unknown composition. CrystEngComm, 10(12), 1728-30. |
| Rights Management |
(c)Royal Society of Chemistry |
| Format Medium |
application/pdf |
| Format Extent |
240,378 bytes |
| Identifier |
ir-main,7718 |
| ARK |
ark:/87278/s6ns1cf3 |
| Setname |
ir_uspace |
| ID |
706062 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6ns1cf3 |
