Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Miller, Joel Steven |
Other Author |
Sugiura, Ken-ichi; Mikami, Shinji; Johnson, Mitchell T.; Iwasaki, Kentaro; Umishita, Kazunori; Hino, Shojun; Sakata, Yoshiteru |
Title |
Structure and magnetic properties of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano 2,5-dimethyl-p-quinodimethanide with a 2.3 K Tc. The first example of cis-coordination of a tetracyano-p-quinodimethanide |
Date |
2000 |
Description |
The crystal structure of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano-2,5-dimethyl-p-quinodimethanide, [MnTMesP][DMTCNQ]-2p-C6H4Me2 provides the first example of a cis-1,2-u-coordination motif having an infinite zigzag chain structure. [MnTMesP][DMTCNQ]-2p-C6H4Me2 crystallizes in a triclinic P1 space group. The zigzag one-dimensional (1-D) chain is non-uniform and each acceptor does not lie on a centre of symmetry, although all acceptors are crystallographically equivalent. The ionic ground state of the complex was determined on the basis of X-ray photoelectron spectroscopy, crystallographic data, as well as the vCN at 2184 and 2160 cm-1. |
Type |
Text |
Publisher |
Royal Society of Chemistry |
First Page |
959 |
Last Page |
964 |
Subject |
Magnets; Interactions; Coupling |
Language |
eng |
Bibliographic Citation |
Sugiura, K., Mikami, S., Johnson, M. T., Miller, J. S., Iwasaki, K., Umishita, K., Hino, S., & Sakata, Y. (2000). Structure and magnetic properties of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano-2,5-dimethyl-p-quinodimethanide with a 2.3 K Tc. The first example of cis-coordination of a tetracyano-p-quinodimethanide. Journal of Materials Chemistry, 10, 959-64. |
Rights Management |
©Royal Society of Chemistry |
Format Medium |
application/pdf |
Format Extent |
227,181 bytes |
Identifier |
ir-main,5422 |
ARK |
ark:/87278/s6st874n |
Setname |
ir_uspace |
ID |
704268 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6st874n |