Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Stang, Peter J. |
Other Author |
Halton, Brian; Kay, Andrew J.; McNichols, Aileen T.; Apeloig, Yitzhak; Boese, Roland; Maulitz, Andreas H.; Haumann, Thomas |
Title |
Studies in the cycloproparene series: cycloaddition reactions of diarylmethylidenecycloproparenes |
Date |
2001 |
Description |
Diarylmethylidenecyclopropanaphthalenes 4b-d add diphenylisobenzofuran (DPIBF) and α-pyrone across the exocyclic double bond to give ring expanded products 11b-d and 13b-d that result from subsequent relief of ring strain in the non-isolable spirocyclic intermediates 10 and 12, respectively. The benzene homologues 3b and 3c add DPIBF across the bridge bond to give the norcaradiene adducts 19b and 19c. |
Type |
Text |
Publisher |
Arkat USA Inc. |
Volume |
2001 |
Issue |
7 |
First Page |
8 |
Last Page |
31 |
Subject |
Cycloproparene series; Cycloaddition; Diarylmethylidenecycloproparenes; Ab initio calculations; Strained aromatics; Acetylenic-iodonium salts; Crystal structures; Cyclobutanes, Diels-Alder cycloaddition; norcaradienes |
Subject LCSH |
Polymers; Molecular structure; Ring formation (Chemistry); Heterocyclic compounds; X-ray crystallography |
Language |
eng |
Bibliographic Citation |
Halton, B., Kay, A. J., McNichols, A. T., Stang, P. J., Apeloig, Y., Boese, R., Maulitz, A. H., & Haumann, T. (2001). Studies in the cycloproparene series: cycloaddition reactions of diarylmethylidenecycloproparenes. Arkivoc, 2001(7), 8-31. |
Rights Management |
(c)Halton, B., Kay, A. J., McNichols, A. T., Stang, P. J., Apeloig, Y., Boese, R., Maulitz, A. H., & Haumann, T. |
Format Medium |
application/pdf |
Format Extent |
267,921 bytes |
Identifier |
ir-main,9020 |
ARK |
ark:/87278/s6nk3zcx |
Setname |
ir_uspace |
ID |
704564 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6nk3zcx |