| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Liyanage, Rohana; Conceição, J. |
| Title |
Guided ion beam studies of the reactions of Vn+ (n = 2-13) with D2: cluster-deuteride bond energies as a chemical probe of cluster electronic structure |
| Date |
2002 |
| Description |
The kinetic energy dependencies of the reactions of Vn+ (n=2 - 13) with D2 are studied in a guided ion beam tandem mass spectrometer. Products observed are VnD1 for all clusters and VnD2 + for n=4 - 13. All reactions are observed to exhibit thresholds, except for formation of VnD2 + for n =4,5,7,9,11- 13. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
116 |
| Issue |
3 |
| First Page |
936 |
| Last Page |
945 |
| DOI |
10.1063/1.1428342 |
| citatation_issn |
219606 |
| Subject |
Metal clusters; Vanadium ions; Bond energies; Endothermic reactions; Collision-induced dissociation; Transition metal ions; Deuterides |
| Subject LCSH |
Thermochemistry; Excited state chemistry; Vanadium; Deuterium |
| Language |
eng |
| Bibliographic Citation |
Liyanage, R., Conceição, J., & Armentrout, P. B. (2002). Guided ion beam studies of the reactions of Vn+ (n = 2-13) with D2: cluster-deuteride bond energies as a chemical probe of cluster electronic structure. Journal of Chemical Physics, 116(3), 936-45. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Liyanage, R., Conceição, J., & Armentrout, P. B., Journal of Chemical Physics, 116(3), 2002 and may be found at http://dx.doi.org/10.1063/1.1428342 |
| Format Medium |
application/pdf |
| Format Extent |
24,492 bytes |
| Identifier |
ir-main,8038 |
| ARK |
ark:/87278/s6b57341 |
| Setname |
ir_uspace |
| ID |
704967 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6b57341 |
