| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Griffin, James B. |
| Title |
Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energies |
| Date |
1998 |
| Description |
The kinetic energy dependence of the reactions of Crn+ (n=1-18) with CO2 are studied in a guided ion beam mass spectrometer. The primary product ions are CrnO+, which then decompose by sequential loss of chromium atoms as the kinetic energy is increased. Simple collision-induced dissociation to form the Crn+-1 product ions is also observed. Large cluster ions, n≥9, form the CrnCO2+ adduct at low kinetic energies. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
108 |
| Issue |
19 |
| First Page |
8075 |
| Last Page |
8083 |
| DOI |
10.1063/1.476246 |
| citatation_issn |
219606 |
| Subject |
Metal clusters; Chromium ions; Oxygen; Bond energies; Exothermic reactions; Endothermic reactions |
| Subject LCSH |
Oxidation; Thermochemistry; Excited state chemistry |
| Language |
eng |
| Bibliographic Citation |
Griffin, J. B., & Armentrout, P. B. (1998). Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energies. Journal of Chemical Physics, 108(19), 8075-83. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Griffin, J. B., & Armentrout, P. B., Journal of Chemical Physics, 108(19), 1998 and may be found at http://dx.doi.org/10.1063/1.476246 |
| Format Medium |
application/pdf |
| Format Extent |
66,372 bytes |
| Identifier |
ir-main,8102 |
| ARK |
ark:/87278/s6dj601g |
| Setname |
ir_uspace |
| ID |
705240 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6dj601g |
