OCR Text |
Show TABLE 1. KINETIC MODEL REACTIONS CONSIDERED SPECIES CH4, CH3, CH2, CH, CH20, HCO, C02, CO, H2, H, 02, 0, OH, H02, H202, H20, C2H6, CH20H, CH30, CH2CO, C, N2, NO, N, NH, NH2, HNO, HCN, NCO, CN, N20, NNH, HNCO, N02, HOCN, HCNO, H2CN, NH3 1.CH3+CH3+M=C2H6+M 2.CH3+H+M=CH4+M 3.H4+02=CH3+H02 4.CH4+H=CH3+H2 5.CH4+0H=CH3+H20 6.CH4+H02=CH3+H202 7.CH3+H02=CH30+0H 8.CH3+02=CH30+0 9.CH3+0=CH20+H 10.CH20H+H=CH3+0H 11.CH30+H=CH3+0H 12.CH3+0H=CH2+H20 13.CH3+H=CH2+H2 14.CH30+M=CH20+H+M 15.CH20H+M=CH20+H+M 16.CH30+H=CH20+H2 17.CH20H+H=CH20+H2 18.CH30+0H=CH20+H20 19.H20H+OH=CH20+H20 20.CH30+0=CH20+0H 21.CH20H+0=CH20+0H 22.CH30+02=CH20+H02 23.CH20H+02=CH20+H02 24CH2+H=CH+H2 25.CH2+0H=CH+H20 26.CH2+0H=CH20+H 27.CH+02=HCO+0 28.CH+0=CO+H 29.CH+OH=HCO+H 30.CH+C02=HCO+CO 31.CH+H=C+H2 32.CH+H20=CH20+H 33.CH+CH20=CH2CO+H 34.C+02=CO+0 35.C+OH=CO+H 36.CH2+C02=CH20+CO 37.CH2+0=CO+H+H 38.CH2+0=CO+H2 39.CH2+02=C02+H+H 40.CH2+02=CH20+0 41.CH2+02=C02+H2 42.H2+02=CO+H20 43.CH2+02=CO+OH+H 44.CH2+02=HCO +OH 45.CH20+0H=HCO+H20 46.CH20+H=HCO+H2 47.H20+M=HCO+H+M 48.CH20+0=HCO+OH 49.HCO+OH=H20+CO 50. HCO+M=H+CO+M 51.HCO+H=CO+H2 52.HCO+0=CO+OH 53. HCO+0=C02+H 54. HCO+02=H02+CO REACTIONS 55.CO+0+M=C02+M 56.CO+OH=C02+H 57.CO+02=C02+0 58.H02+CO=C02+0H 59.CH2CO+0=C02+CH2 60.CH2CO+H=CH3+CO 61.CH2CO+M=CH2+CO+M 62.H2+02=20H 63.0H+H2=H20+H 64.0+0H=02+H 65.0+H2=OH+H 66.H+02+M=H02+M 67.0H+H02=H20+02 68.H+H02=20H 69.0+H02=02+0H 70. H02+H=0+H20 71.H+H+M=H2+M 72.H+H+H2=H2+H2 73.H+H+H20=H2+H20 74.H+H+C02=H2+C02 75.H+OH+M=H20+M 76.H+0+M=OH+M 77.0+0+M=02+M 78.H+H02=H2+02 79.H02+H02=H202+02 80.H202+M=OH+OH+M 81.H202+H=H02+H2 82.H202+0H=H20+H02 83.CH+N2=HCN+N 84.CN+N=C+N2 85.CH2+N2=HCN+NH 86.H2CN+N=N2+CH2 87.H2CN+M=HCN+H+M 88.C+NO=CN+0 89.CH+NO=HCN+0 90.CH2+NO=HCNO+H 91.CH3+NO=HCN+H20 92.CH3+NO=H2CN+OH 93.HCNO+H=HCN+OH 94.CH2+N=HCN+H 95.CH+N=CN+H 96.C02+N=NO+CO 97.HCN+OH=CN+H20 98.0H+HCN=HOCN+H 99.0H+HCN=HNCO+H 100.0H+HCN=NH2+CO 101.HOCN+H=HNCO+H 102.HCN+0=NCO+H 103.HCN+0=NH+CO 104.HCN+0=CN+OH 105.CN+H2=HCN+H 106.CN+0=CO+N 107.CN+02=NCO+0 108.CN+OH=NCO+H 9 109.CN+N02=NCO+NO 110.CN+N20=NCO+N2 111.H02+NO=N02+0H 112.N02+H=NO+OH 113.N02+0=NO+02 114.N02+M=NO+0+M 115.NCO+H=NH+CO 116.NCO+0=NO+CO 117.NCO+N=N2+CO 118.NCO+OH=NO+HCO 119.NCO+M=N+CO+M 120.NCO+NO=N20+CO 121. NCO+H2=HNCO+H 122.HNCO+H=NH2+CO 123.HNCO+M=NH+CO 124.HNCO+NH=NH2+NCO 125.HNCO+NH2=NH3+NCO 126.0H+HNCO=NCO+H20 127.HNCO+0=HNO+CO 128.NH+02=HNO+0 129.NH+02=NO+OH 130.NH+NO=N20+H 131.N20+0H=N2+H02 132.N20+H=N2+0H 133.N20+M=N2+0+M 134.N20+0=N2+02 135.N20+0=NO+NO 136.NH+OH=HNO+H 137.NH+OH=N+H20 138.NH+N=N2+H 139.NH+H=N+H2 140.NH2+0=HNO+H 141.NH2+0=NH+OH 142.NH2+0H=NH+H20 143.NH2+H=NH+H2 144.NH2+NO=NNH+OH 145.NH2+NO=N2+H20 146.NH3+0H=NH2+H20 147.NH3+H=NH2+H2 148.NH3+0=NH2+0H 149.NNH=N2+H 150.NNH+NO=N2+HNO 151.NNH+H=N2+H2 152.NNH+OH=N2+H20 153.NNH+NH2=N2+NH3 154.NNH+NH=N2+NH2 155.NNH+0=N20+H 156.HNO+M=H+NO+M 157.HNO+OH=NO+H20 158.HNO+H=H2+NO 159.HNO+NH2=NH3+NO 160.N+NO=N2+0 161.N+02=NO+0 162.N+OH=NO+H |