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Creator | Title | Description | Subject | Date |
101 |
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Miller, Joel Steven; Epstein, Arthur J. | Optical control of magnetic order in molecule-based magnet Mn(TCNE)x.y(CH2Cl2) | Studies of photoinduced magnetization and photoinduced absorption in molecule-based magnet Mn(TCNE)x•y(CH2Cl2) (x=2, y-0.8, TCNE=tetracyanoethylene) are reported. Optical excitation in the blue region of spectrum leads to increased magnetization, accompanied by changes in the electronic spectrum... | Spectrum; Absorption; Illumination | 2002 |
102 |
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Morse, Michael David | Laser vaporization generation of Y ??B+, Y ??B+, and YAI+ for electron spin resonance studies in neon matrices at 4 K: comparison with theoretical calculations | The first spectroscopic investigation of 89Y 10B+, 89Y 11B+, and 89Y 27Al+ is reported, revealing that both of these diatomic cation radicals have X 4?- electronic ground states. The ions were generated by three high energy techniques in combination with neon matrix isolation at 4 K and studied by e... | | 1992 |
103 |
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Miller, Joel Steven | MnII(TCNE)3/2(I3)1/2-A 3D network-structured organic-based magnet and comparison to a 2-D analog | Organic-based magnets utilize unpaired electrons residing on organic species to form magnetically ordered materials. Unlike traditional atom/ion-based magnets, they enable the controllable modulation and combination of magnetic properties with other technologically important properties (e.g., electr... | | 2010 |
104 |
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Morse, Michael David | Spectroscopy and electronic structure of jet-cooled NiPd and PdPt | Resonant two-photon ionization spectroscopy of jet-cooled NiPd and PdPt has revealed a dense vibronic spectrum for NiPd and a much more sparse spectrum for PdPt. Four vibrational progressions have been identified for NiPd, and three have been located for PdPt. High resolution investigations of NiPd... | | 1990 |
105 |
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Armentrout, Peter B. | Reactions of Ta+ and W+ with H2, D2, and HD: effect of lanthanide contraction and spin-orbit interactions on reactivity and thermochemistry | A guided ion beam tandem mass spectrometer is used to examine the kinetic energy dependence of reactions of the third-row transition metal cations, Ta1, and W1, with molecular hydrogen and its isotopologs. A flow tube ion source produces Ta1 and W1 ions in their electronic ground state term and p... | Metal clusters; Tantalum ions; Tungsten ions; Lanthanide contraction; Bond energies; Endothermic reactions; Transition metal ions; Dihydrogen | 2002 |
106 |
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Armentrout, Peter B. | Mechanism of proton exchange: guided ion beam studies of the reactions, H(H2O)n+ (n=1-4) + D2O and D(D 2O)n+ (n=1-4) + H2O | Reactions of protonated water clusters, H(H2O)n+ (n=1-4) with D2O and their "mirror" reactions, D(D2O)n+ (n=1-4) with H2O, are are studied using guided-ion beam mass spectrometry. Absolute reaction cross sections are determined as a function of collision energy from thermal energy to over 10 eV. | Collision-induced dissociation; Proton exchange; Protonated water clusters; Exothermic reactions; Deuterium oxide | 2004 |
107 |
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Morse, Michael David | Spectroscopy of mixed early-late transition metal diatomics: ScNi, YPd, and ZrCo | Resonant two-photon ionization spectroscopy has been employed to investigate the spectra of the jet-cooled transition metal diatomics ScNi, YPd, and ZrCo, which are isovalent species which possess ~or are thought to possess! an X 2?+ ground state. Several electronic band systems have been observed f... | | 1994 |
108 |
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Miller, Joel Steven | [Cyanil]2 2- dimers possess long, two-electron ten-center (2e-/10c) multicenter bonding | A long, two-electron ten-center (2e-/10c) [8 carbon plus 2 oxygen] bond in diamagnetic dimers of radical-anion tetracyano-1,4-benzoquinoneide (cyanil, [Q]2 2-, is described by B2LYP and CASSCF92,2)/MCQDPT calculations. | Carbon bonds; Cyanil | 2008 |
109 |
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Morse, Michael David | Spectrsocopy of Jet-cooled YCu | Optical spectra of jet-cooled diatomic YCu have been recorded using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown experimentally to be of 1?+ symmetry, with a measured bond length of re"=2.6197(6) ? and a vibrational frequency of 193.21(24... | | 1995 |
110 |
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Miller, Joel Steven; Epstein, Arthur J. | Optical properties of quinolinium tetracyanoquinodimethanide, [Qn(TCNQ)2] and (N-methylphenazinium)x(phenazine)1-x (tetracyanoquinodimethane) [(NMP)x(Phen)1-x(TCNQ)] | We present here optical-absorption data of quinolinium ditetracyanoquinodimethanide [Qn(TCNQ)2] and (N-methylphenazinium)x(phenazine)1-x(tetracyanoquinodimethanide) [(NMP)x(Phen)1-x(TCNQ)] for 0.5 <_x<_ 0.6. These materials span the range of electronic structure from commensurate, to commensurate ... | Commensurate; Lattice; Electron | 1989 |
111 |
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Morse, Michael David | Laser excitation spectroscopy of the A and B states of jet-cooled copper dimer: evidence for large electronic isotope shifts | Fluorescence excitation spectra recorded for the A-X system of jet-cooled Cu2 show conclusive evidence of a ?? = 0 transition, and the A state is thereby definitively assigned as ??u+. A previous assignment of the B state as ??u+ is confirmed, but the vibrational levels of this state are complicated... | | 1989 |
112 |
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Miller, Joel Steven | Structural and magnetic characterization of a- and B-2,4-hexadiyne-1,6-diyl Bis(2,2,5,5-tetramethyl-1-oxyl-3-pyrroline-3-carboxylate) and its thermal degradation product | The search for ferromagnetic organic compounds and polymers is the focus of contemporary research.1 - 5 Polymerization of di-iminoxyl diacetylene monomers has been suggested as a means to prepare a high spin potentially ferromagnetically coupled polymers3 and the thermal, photochemical, and glow di... | Ferromagnetic; Magnetization; Polymers | 1989 |
113 |
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Armentrout, Peter B. | Guided ion beam study of collision-induced dissociation dynamics: integral and differential cross sections | The low energy collision-induced dissociation (CID) of Cr(CO)6+ with Xe is investigated using a recently modified guided ion beam tandem mass spectrometer, in the energy range from 0 to 5 eV in the center-of-mass (CM) frame. The additions to the instrument, updated with a double octopole system, and... | Collision-induced dissociation; Bond energies; Chromium carbonyl; Xenon | 2001 |
114 |
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Morse, Michael David | Spectroscopic studies of jet-cooled AINi | Resonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the p... | | 1993 |
115 |
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Miller, Joel Steven | 1H NMR investigation of the magnetic spin configuration in the molecule-based ferrimagnet [MnTFPP][TCNE] | 1H NMR line-shape measurements have been performed in the linear chain molecule-based ferrimagnet [MnTFPP][TCNE].xPhMe (TFPP=tetrakis(4-fluorophenyl)porphinato; TCNE=tetracyanoethylene) as a function of temperature. Hyperfine shifts of opposite sign were observed indicating the presence of two oppo... | Magnetization; Magnets; Paramagnetic | 2002 |
116 |
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Morse, Michael David | Electronic structure of the 4d transition metal carbides: dispersed fluorescence spectroscopy of MoC, RuC, and PdC | Dispersed fluorescence studies of the diatomic molecules MoC, RuC, and PdC are reported. New states identified in MoC and RuC are the [...]2?112?1, 3,1?2 states and the [...]2? 312?1, 1?2 state, respectively. Five states re observed by dispersed fluorescence in PdC. The ground state is found to be [... | | 2001 |
117 |
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Miller, Joel Steven | Structure and magnetic properties of MnII[N(CN)2]2(pyrazine). An antiferromagnet with an interpenetrating 3-D network structure | Mn[N(CN)2]2(pyz) (pyz = pyrazine) orders antiferromagnetically at low temperature and possesses intralayer u-NCNCN and interlayer u-pyz ligands that form a pseudo-ReO3 interpenetrating network structure. | Dicyanamide; Polydentate; Temperature | 1998 |
118 |
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Miller, Joel Steven | Structure and magnetic properties of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano 2,5-dimethyl-p-quinodimethanide with a 2.3 K Tc. The first example of cis-coordination of a tetracyano-p-quinodimethanide | The crystal structure of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano-2,5-dimethyl-p-quinodimethanide, [MnTMesP][DMTCNQ]-2p-C6H4Me2 provides the first example of a cis-1,2-u-coordination motif having an infinite zigzag chain structure. [MnTMesP][DMTCNQ]-2p-C6H4Me... | Magnets; Interactions; Coupling | 2000 |
119 |
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Miller, Joel Steven | [Et4N]2[TCNE]2 (TCNE = tetracyanoethylene) - an example of an exceptionally long 2.827 Ã CC bond | Interest in organic compounds exhibiting unusually long CC bonds has been the subject of several recent studies.1-3 The longest sp3-sp3 C-C single bond reported to date is 1.73 A°,1,2 whereas several [TCNE]22- (TCNE = tetracyanoethylene) dimers have been recently reported to form cation-assisted, l... | Synthesis; Crystal; Solution | 2001 |
120 |
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Armentrout, Peter B. | Guided ion beam and theoretical studies of the reaction of Ag+ with CS2: gas-phase thermochemistry of AgS+ and AgCS+ and insight into spin-forbidden reactions | The gas-phase reactivity of the atomic transition metal cation, Ag+, with CS2 is investigated using guided-ion beam mass spectrometry. Endothermic reactions forming AgS+ and AgCS+ are observed but are quite inefficient. This observation is largely attributed to the stability of the closed shell Ag+(... | | 2010 |
121 |
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Miller, Joel Steven; Epstein, Arthur J. | Organic and molecular ferromagnets | Unlike common ferromagnets such as iron, nickel, cobalt or even cobalt-samarium and Nb-Fe-B, it is extremely rare for a discrete molecule, especially an organic or polymeric material, to have cooperative magnetic interactions. Since the mid-1980s a few such materials have been prepared which demon... | Magnetic; Magnetization; Temperature | 1992 |
122 |
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Morse, Michael David | Spectrosopic studies of jet-cooled NiAu and PtCu | Spectroscopic investigations of NiAu and PtCu have revealed that both molecules possess 2?5/2 ground electronic states, and are in this respect analogous to the isovalent molecule NiCu. The ground-state bond lengths (r?) have been measured as 2.351?0.001 ? and 2.335?0.001 ? for NiAu and PtCu, respe... | | 1992 |
123 |
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Morse, Michael David | Predissociation lifetimes of vibrational levels of the excited ? B? (Ka=O) electronic states of Cd ? H? and Cd ? D? complexes | The experimental rates of predissociation of vibrational levels of the ?B? (K'a-O) excited states of the Cd ? HZ and Cd ? D2 complexes are shown to be consistent with both semiclassical and quantum-mechanical pseudodiatomic theoretical treatments of the process. The ?B? pseudodiatomic potential was ... | | 1992 |
124 |
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Morse, Michael David | Rotationally resolved spectra of jet-cooled RuSi | We report the first gas-phase spectroscopic investigation of diatomic ruthenium silicide (RuSi). The molecules were produced by laser ablation of a Ru disk into a flow of helium carrier gas containing 0.5% SiH4, and were cooled in a supersonic expansion. The RuSi molecules were then studied using re... | | 2007 |
125 |
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Miller, Joel Steven; Epstein, Arthur J. | Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited) | A new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-l-oxy) butadiyne has been prepared and characterized by x-ray diffraction, infrared and Raman spectroscopies, and magnetic susceptibility. Unlike t h e Pccn-a phase, the B phase belongs to the Pca2y1 space group [a = 14.265(1) A(o),b ... | Molecular; Magnetic; Thermal | 1988 |