1 - 25 of 288
Number of results to display per page
TitleCreatorDescriptionSubjectDate
1Rotational analysis of the 30 1 band of the Ã6Σ+ ← X̃6Σ + system of CrCCHRotational analysis of the 30 1 band of the Ã6Σ+ ← X̃6Σ + system of CrCCHMorse, Michael DavidThe spectrum of chromium acetylide, CrCCH, has been investigated in the near-infrared region (10 500-14 500 cm−1) and an intense band system is observed. The 310 band of this system has been investigated at high resolution (0.025 cm−1) and this system is identified as the ˜A6 + ← ˜X6 + syste...2014-01-01
2Atomic scale trap state characterization by dynamic tunneling force microscopyAtomic scale trap state characterization by dynamic tunneling force microscopyWilliams, Clayton C.Dynamic tunneling force microscopy (DTFM) is applied to the study of point defects in an inter-layer dielectric film. A recent development enables simultaneous acquisition of DTFM, surface potential, and topographic images while under active height feedback control. The images show no clear correlat...2014-01-01
3The bond energy of ReO+: Guided ion-beam and theoretical studies of the reaction of Re+ (7S) with O2The bond energy of ReO+: Guided ion-beam and theoretical studies of the reaction of Re+ (7S) with O2Armentrout, Peter B.The kinetic-energy dependence of the Re+ + O2 reaction is examined using guided ion-beam mass spectrometry. The cross section for ReO+ formation from ground state Re+ (7S) is unusual, exhibiting two endothermic features. The kinetic energy dependence for ReO+ formation is analyzed to determine D0(Re...2013-01-01
4A contribution to the many-fermion problemA contribution to the many-fermion problemMattis, Daniel C.In this work we reexamine the many-fermion problem in arbitrary dimensions. It is shown that in two dimensions or higher, the Hamiltonian of interacting fermions can be separated into individual nonintersecting sectors labeled by the wave-vector q. Within each sector the Hamiltonian maps onto a gene...2012-01-01
5Magnetic-field dependent differential capacitance of polymer diodesMagnetic-field dependent differential capacitance of polymer diodesRogachev, AndreyUsing admittance spectroscopy, we found that bipolar organic diodes based on pi-conjugated polymer, 2-methoxy-5-(20-ethylhexyloxy), MEH-PPV, have strong divergent contribution to the device differential capacitance. It is positive at low bias voltages, turns negative at intermediate biases, and beco...2012-01-01
6Admittance spectroscopy study of polymer diodes in small magnetic fieldsAdmittance spectroscopy study of polymer diodes in small magnetic fieldsRogachev, AndreyWe performed a systematic study of bipolar and unipolar organic diodes based on the p-conjugated polymer, 2-methoxy-5-(20-ethylhexyloxy) (MEH-PPV), using electronic and magneto-transport measurements with magnetic field in the range 0-180mT and admittance spectroscopy in the frequency range 1 Hz<f<1...2012-01-01
7The lsing model and critical behavior of transport in binary composite mediaThe lsing model and critical behavior of transport in binary composite mediaGolden, Kenneth M.We present a general theory for critical behavior of transport in binary composite media. The theory holds for lattice and continuum percolation models in both the static case with real parameters and the quasi-static case (frequency dependent) with complex parameters. Through a direct, analytic cor...2012-01-01
8Probing the electrode-polymer interface in conjugated polymer devices with surface-enhanced Raman scatteringProbing the electrode-polymer interface in conjugated polymer devices with surface-enhanced Raman scatteringLupton, John MarkA crucial consideration in organic devices is the role of the interface between a metal electrode and the active polymer material. Here, we use the conjugated polymer poly[2-methoxy-5-(2-ethylhexyl-oxy)-1,4-phenylene-vinylene] (MEH-PPV) with model gold and silver electrodes to perform surface-enhanc...2012-01-01
9Guided ion beam and theoretical study of the reactions of Hf+ with H2, D2, and HDGuided ion beam and theoretical study of the reactions of Hf+ with H2, D2, and HDArmentrout, Peter B.The kinetic energy dependences of reactions of the third-row transition metal cation Hf+ with H2, D2, and HD were determined using a guided ion beam tandem mass spectrometer. A flow tube ion source produces Hf+ in its 2D (6s25d1) electronic ground state level. Corresponding state-specific reaction c...2010-01-01
10Self-switching Q-damping circuit for reducing transmitter ringdown time in high power pulse NMRSelf-switching Q-damping circuit for reducing transmitter ringdown time in high power pulse NMRAilion, David CharlesIn this paper we describe a circuit for reducing the transmitter ringdown time and thereby improving the recovery time in pulse NMR experiments. The circuit uses only solid state devices and requires no external switching. For transmitter voltages less than 0.5 V peak to peak the effective resista...Circuits; NMR experiments; Rf pulse1970
11Quantitative assessment of the accuracy of centroid molecular dynamics for the calculation of the infrared spectrum of liquid waterQuantitative assessment of the accuracy of centroid molecular dynamics for the calculation of the infrared spectrum of liquid waterVoth, Gregory AlanA detailed analysis of the infrared lineshapes corresponding to the intramolecular bond vibrations of HOD in either H2O or D2O is presented here in order to quantitatively assess the accuracy of centroid molecular dynamics in reproducing the correct features of the infrared spectrum of water at amb...2010
12Quantitative two-dimensional dopant profile measurement and inverse modeling by scanning capacitance microscopyQuantitative two-dimensional dopant profile measurement and inverse modeling by scanning capacitance microscopyWilliams, Clayton C.; Huang, YufengQuantitative dopant profile measurements are performed on a nanometer scale by scanning capacitance microscopy (SCM). An atomic force microscope is used to position a nanometer scale tip at a semiconductor surface, and local capacitance change is measured as a function of sample bias. A new feedback...Dopant profile; Capacitance change; Scanning capacitance microscopy; Feedback control1995
13Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited)Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited)Miller, Joel Steven; Epstein, Arthur J.A new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-l-oxy) butadiyne has been prepared and characterized by x-ray diffraction, infrared and Raman spectroscopies, and magnetic susceptibility. Unlike t h e Pccn-a phase, the B phase belongs to the Pca2y1 space group [a = 14.265(1) A(o),b ...Molecular; Magnetic; Thermal1988
14Direct ab initio dynamics studies of N + H2<-->NH + H reactionDirect ab initio dynamics studies of N + H2<-->NH + H reactionTruong, ThanhKinetics of the N+H2<-->NH+H reaction have been studied using a direct ab initio dynamics method. Potential energy surface for low electronic states have been explored at the QCISD/ cc-pVDZ level of theory. We found the ground-state reaction is N(4S)+H2-->NH(3Σ-)+H. Thermal rate constants for this ...Ab initio dynamics; Potential energy surfaces; Minimum energy path; Ground-state reaction; Rate constants2000
15Direct comparison of cross-sectional scanning capacitance microscope dopant profile and vertical secondary ion-mass spectroscopy profileDirect comparison of cross-sectional scanning capacitance microscope dopant profile and vertical secondary ion-mass spectroscopy profileWilliams, Clayton C.; Huang, YufengThe scanning capacitance microscope (SCM) has been shown to be useful for quantitative 2D dopant profiling near the surface of silicon. An atomic force microscope is used to position a nanometer scale tip at a silicon surface, and local capacitance change is measured as a function of sample bias. A ...Oxide capacitance; Dopant profile; Oxide layer; Scanning capacitance microscopy1996-01
16Direct imaging of SiO2 thickness variation on Si using modified atomic force microscopeDirect imaging of SiO2 thickness variation on Si using modified atomic force microscopeWilliams, Clayton C.Fabrication techniques of metal-oxide-semiconductor ~(MOS) transistors have been improved very rapidly during the last several decades. With this trend, scaling down of MOS transistors is necessary to improve the speed of circuits and the packing density of discrete devices. Both lateral and vertic...Silicon dioxide; Oxide layer; Phosphorus ions; Oxide capacitance; Dopant profile1996-03-01
17Directional emission from asymmetric microlaser resonators of ∏-conjugated polymersDirectional emission from asymmetric microlaser resonators of ∏-conjugated polymersVardeny, Zeev ValentineA ∏-conjugated polymer film was fabricated into an asymmetric microlaser resonator having a quadrapole deformation with irregular boundaries and a Q factor of 600. At high excitation intensities above the threshold for lasing, we observed multimode laser emission spectra and directional emission a...Directional emission; Asymmetric microlaser resonators; pi-conjugated polymers; DOO-PPV; poly(dioctyloxy) phenylene vinylene2004
183He spin exchange cells for magnetic resonance imaging3He spin exchange cells for magnetic resonance imagingSaam, BrianWe present a protocol for the consistent fabrication of glass cells to provide hyperpolarized (HP) 3He for pulmonary magnetic resonance imaging. The method for producing HP 3He is spin-exchange optical pumping. The valved cells must hold of order 1 atm.L of gas at up to 15 atm pressure. Because char...3He; Spin exchange cells; Hyperpolarized 3He; Pulmonary magnetic resonance imaging; Spin-exchange optical pumping; SEOP; Glass cells2002
19Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+Morse, Michael DavidThe bond dissociation energies of Ti2+, V+2 , Co+2, and Co: have been measured from the sudden onset of predissociation in the photodissociation spectra of these molecules, yielding values of D?(Ti+2)=2.435+0.002 eV, D?(V+2)=3.140?0.002 eV, D?(Co+2)=2.7651?0.001 eV, and D?(Co+3)=2.086?0.002 eV. Thes...1993
20Resonant two-photon ionization spectroscopy of jet-cooled Pt?Resonant two-photon ionization spectroscopy of jet-cooled Pt?Morse, Michael DavidThe gas phase optical spectrum of jet-cooled Pt? has been investigated over the range of 11 300 to 26 300 cm -1 using resonant two-photon ionization spectroscopy in combination with time-of-flight mass spectrometry. Numerous vibronic bands are observed. Analysis of the data gives the location of som...1988
21Interaction of an aluminum atom with a closed subshell metal atom: spectroscopic analysis of AIZnInteraction of an aluminum atom with a closed subshell metal atom: spectroscopic analysis of AIZnMorse, Michael DavidResonant two-photon ionization spectroscopy has been employed to investigate diatomic AlZn produced by laser vaporization of a 1:2 Al:Zn alloy target disk in a supersonic expansion of helium. Several discrete transitions are reported in the energy range from 18 400 to 19 100 cm-?. Most of these are...1994
22Spectroscopic studies of jet-cooled AINiSpectroscopic studies of jet-cooled AINiMorse, Michael DavidResonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the p...1993
23Guided ion beam and theoretical studies of the reaction of Ag+ with CS2: gas-phase thermochemistry of AgS+ and AgCS+ and insight into spin-forbidden reactionsGuided ion beam and theoretical studies of the reaction of Ag+ with CS2: gas-phase thermochemistry of AgS+ and AgCS+ and insight into spin-forbidden reactionsArmentrout, Peter B.The gas-phase reactivity of the atomic transition metal cation, Ag+, with CS2 is investigated using guided-ion beam mass spectrometry. Endothermic reactions forming AgS+ and AgCS+ are observed but are quite inefficient. This observation is largely attributed to the stability of the closed shell Ag+(...2010
24Guided ion beam studies of the reaction of Nin+ (n=2-16) with D2: nickel cluster-deuteride bond energiesGuided ion beam studies of the reaction of Nin+ (n=2-16) with D2: nickel cluster-deuteride bond energiesArmentrout, Peter B.The kinetic-energy dependences of the reactions of Nin+ (n=2-16) with D2 are studied in a guided ion beam tandem mass spectrometer. The products observed are NinD+ for all clusters and NinD2 + for n=5-16. Reactions for formation of NinD+ are observed to exhibit thresholds, whereas cross sections for...Metal clusters; Nickel ions; Bond energies; Deuterides; Collision-induced dissociation; Endothermic reactions2002
25Guided ion beam studies of the reactions of Crn + (n=2-18) with O2: chromium cluster oxide and dioxide bond energiesGuided ion beam studies of the reactions of Crn + (n=2-18) with O2: chromium cluster oxide and dioxide bond energiesArmentrout, Peter B.The kinetic energy dependence of the reactions of Crn+ (n=2-18) with O2 are studied in a guided ion beam mass spectrometer. A variety of CrmO2+, CrmO+, and Crm+ product ions, where m≤n, are observed, with the dioxide cluster ions dominating the products for all larger reactant cluster ions. React...Metal clusters; Chromium ions; Oxygen; Oxygen; Bond energies; Exothermic reactions1998
1 - 25 of 288