| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Beauchamp, J. L. |
| Title |
Cobalt carbene ion: reactions of Co+ with C2H4, cyclo-C3H6 and cyclo-C2H4O |
| Date |
1981 |
| Description |
An ion beam apparatus is employed to study the formation of the cobalt carbene ion, CoCH2+. This ion is produced in the endothermic reaction of cobalt ions with ethene and cyclopropane and in an exothermic reaction with ethylene oxide. A model is proposed to account for the dependence of experimental cross sections on relative kinetic energy for the endothermic reactions. Using this model to interpret the experimental results, a bond dissociation energy D°(Co+-CH2 ) = 3.7+0.3 eV is derived. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
74 |
| Issue |
5 |
| First Page |
2819 |
| Last Page |
2826 |
| DOI |
10.1063/1.441453 |
| citatation_issn |
219606 |
| Subject |
Cobalt carbine; Ion beam; Bond dissociation energy; Reaction cross section; Endothermic reactions |
| Subject LCSH |
Ion bombardment; Carbenes; Transition metal compounds |
| Language |
eng |
| Bibliographic Citation |
Armentrout, P. B. & Beauchamp, J. L. (1981). Cobalt carbene ion: reactions of Co+ with C2H4, cyclo-C3H6 and cyclo-C2H4O. Journal of Chemical Physics, 74(5), 2819-26. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Armentrout, P. B. & Beauchamp, J. L., Journal of Chemical Physics, 74(5), 1981 and may be found at http://dx.doi.org/10.1063/1.441453. |
| Format Medium |
application/pdf |
| Format Extent |
765,542 bytes |
| Identifier |
ir-main,7035 |
| ARK |
ark:/87278/s6t7323p |
| Setname |
ir_uspace |
| ID |
707472 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6t7323p |
