Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Russon, Larry M.; Heidecke, Scott A.; Birke, Michelle K.; Armentrout, P. B.
Title Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+
Date 1993
Description The bond dissociation energies of Ti2+, V+2 , Co+2, and Co: have been measured from the sudden onset of predissociation in the photodissociation spectra of these molecules, yielding values of D?(Ti+2)=2.435+0.002 eV, D?(V+2)=3.140?0.002 eV, D?(Co+2)=2.7651?0.001 eV, and D?(Co+3)=2.086?0.002 eV. These values are in good agreement with values previously determined from collision-induced dissociation experiments. General criteria for the interpretation of predissociation thresholds as bond dissociation energies and periodic trends in the bonding of the 3d transition metal diatomic neutrals and monocations are discussed.
Type Text
Publisher American Institute of Physics (AIP)
Volume 100
Issue 7
First Page 4747
Last Page 4755
DOI 10.1063/1.466265
Language eng
Bibliographic Citation Russon, L. M., Heidecke, S. A., Birke, M. K., Morse, M. D., & Armentrout, P. B. (1993). Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+. Journal of Chemical Physics, 100(7), 4747-55.
Rights Management ¬©American Institute of Physics. The following article appeared in Russon, L. M., Heidecke, S. A., Birke, M. K., Morse, M. D., & Armentrout, P. B. (1993). Photodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+. Journal of Chemical Physics, 100(7), 4747-55. and may be found at http://dx.doi.org/10.1063/1.466265.
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Identifier ir-main,16945
ARK ark:/87278/s6rj536p
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 707426
Reference URL https://collections.lib.utah.edu/ark:/87278/s6rj536p
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