| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Li, Feng-Xia |
| Title |
Activation of methane by gold cations: guided ion beam and theoretical studies |
| Date |
2006 |
| Description |
The potential energy surface for activation of methane by the third-row transition metal cation, Au+, is studied experimentally by examining the kinetic energy dependence of this reaction using guided ion beam tandem mass spectrometry. A flow tube ion source produces Au+ primarily in its 1S0 (5d10) electronic ground state level but with some 3D (and perhaps higher lying) excited states that can be completely removed by a suitable quenching gas (N2O). |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
125 |
| Issue |
13 |
| First Page |
133114 |
| DOI |
10.1063/1.2220038 |
| citatation_issn |
219606 |
| Subject LCSH |
Methane; Transition metal ions; Catalysis; Excited state chemistry; Surface chemistry; Potential energy surfaces |
| Language |
eng |
| Bibliographic Citation |
Li, F.-X., & Armentrout, P. B. (2006). Activation of methane by gold cations: guided ion beam and theoretical studies. Journal of Chemical Physics, 125(13), no. 133114. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Li, F.-X., & Armentrout, P., Journal of Chemical Physics, 125(13), 2006 and may be found at http://dx.doi.org/10.1063/1.2220038. |
| Format Medium |
application/pdf |
| Format Extent |
49,638 bytes |
| Identifier |
ir-main,7959 |
| ARK |
ark:/87278/s6mg8736 |
| Setname |
ir_uspace |
| ID |
706514 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6mg8736 |
