Far-infrared powder spectrum of (N(CH3)3D)(I)(TCNQ)

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Miller, Joel Steven
Other Author Eldridge, J. E.; Fortier, Normand; Bates, Frances E.
Title Far-infrared powder spectrum of (N(CH3)3D)(I)(TCNQ)
Date 1983
Description We present the powder absorption spectrum of (TMA)(I)(TCNQ) in the far-infrared as a function of temperature. Below 160 K new absorption features appear and others increase in intensity. This behaviour supports the electron- neutron-diffraction evidence of a distortion on the TCNQ chains below the first phase-transition temperature. Effects due to the second phase transition at 89 K are also observed. The results of a group-theoretical analysis are presented. These show that totally-symmetric internal modes ag are to be expected in the infrared spectra of this compound even in the undistorted phase.
Type Text
Publisher National Research Council Canada Research Press
Volume 61
Issue 9
First Page 1271
Last Page 1277
Subject Conductivity, Crystals, Electrons
Language eng
Bibliographic Citation Eldridge, J. E., Fortier, N., Bates, F. E., & Miller, J. S. (1983). Far-infrared powder spectrum of (N(CH3)3D)(I)(TCNQ). Canadian Journal of Physics, 61(9), 1271-7.
Rights Management (c) National Research Council Canada Research Press
Format Medium application/pdf
Format Extent 3,374,505 bytes
Identifier ir-main,5276
ARK ark:/87278/s6pr8dh1
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 706438
Reference URL https://collections.lib.utah.edu/ark:/87278/s6pr8dh1
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