One-dimensional coordination polymers based on first-row transition metals: a solid-state study of weak backbone interactions

Update Item Information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Stang, Peter J.
Other Author Seidel, S. Russell; Tabellion, Frank M.; Arif, Atta M.
Title One-dimensional coordination polymers based on first-row transition metals: a solid-state study of weak backbone interactions
Date 2001
Description We present further data on the solid-state structures of one-dimensional coordination polymers based upon dipositive transition metal hexafluoroacetylacetonate (hfacac) complexes. A variety of linking subunits are employed in order to investigate and probe the relatively weak interactions that make up the backbones of these polymers. Reported in this study are metal complexes containing manganese, zinc, copper, and cobalt and a range of donor building blocks encompassing an array of bonding motifs, including pyridyl-metal, pyridyl(N-oxide)-metal, and hydrogen bonding. The specific linkers utilized are 4,4′-dipyridyl N,N′- dioxide hydrate, 2,5-bis(4-ethynylpyridyl)furan, 4,4′-trimethylenedipyridine, and trans-1-(2-pyridyl)-2-(4-pyridyl)-ethylene. A detailed discussion of the products is presented, as is a comparison to known compounds of a similar nature. All compounds are characterized via single-crystal X-ray diffraction and elemental analysis for the bulk of the sample.
Type Text
Publisher Laser Pages Publishing Ltd.
Volume 41
Issue 3
First Page 149
Last Page 161
Subject Hexafluoroacetylacetonate complexes; Coordination polymers
Subject LCSH Transition metal complexes; Polymers; Molecular structure
Language eng
Bibliographic Citation Seidel, S. R., Tabellion, F. M., Arif, A. M., & Stang, P. J. (2001). One-dimensional coordination polymers based on first-row transition metals: a solid-state study of weak backbone interactions. Israel Journal of Chemistry, 41(3), 149-61.
Rights Management (c)Laser Pages Publishing Ltd.
Format Medium application/pdf
Format Extent 673,075 bytes
Identifier ir-main,9016
ARK ark:/87278/s6j39b3d
Setname ir_uspace
ID 706241
Reference URL https://collections.lib.utah.edu/ark:/87278/s6j39b3d
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