Magnetic behavior of octaethylporphyrinatomanganese(III) tetracyanoethenide, [MnOEP][TCNE], and hexacyanobutadienide, [MnOEP][C4(CN)6]: the importance of a uniform chain for stabilizing strong effective ferromagnetic coupling

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Miller, Joel Steven; Epstein, Arthur J.
Other Author Vazquez, Carlos; Jones, Nancy L.; McLean, R. Scott
Title Magnetic behavior of octaethylporphyrinatomanganese(III) tetracyanoethenide, [MnOEP][TCNE], and hexacyanobutadienide, [MnOEP][C4(CN)6]: the importance of a uniform chain for stabilizing strong effective ferromagnetic coupling
Date 1995
Description [MnOEP][A] {A=[TCNE]'- and [C4(CN)6]'-} have been isolated as extended 1D coordination polymers with trans-U2"[A] bridging ligands with strong {A=[C4(CN)6].-} and weak {A=TCNE].-} ferromagnetic coupling as evidenced from the fit of the magnetic susceptibility to the Curie-Weiss law (0=5.1 and 67.1 K, respectively); the strong behaviour arises from the presence of uniform chains which are not present for the [TCNE]'- salt.
Type Text
Publisher Royal Society of Chemistry
Volume 4
Issue CN)6]: the importance of a uniform chain for stabilizing strong effective ferromagnetic coupling. Journal of Materials Chemistry, 5(5
First Page 707
Last Page 711
Subject Crystals; Inversion; Coupling
Language eng
Bibliographic Citation Miller, J. S., Vazquez, C., Jones, N. L., McLean, R. S., & Epstein, A. J. (1995). Magnetic behavior of octaethylporphyrinatomanganese(III) tetracyanoethenide, [MnOEP][TCNE], and hexacyanobutadienide, [MnOEP][C4(CN)6]: the importance of a uniform chain for stabilizing strong effective ferromagnetic coupling. Journal of Materials Chemistry, 5(5), 707-11.
Rights Management (c)Royal Society of Chemistry
Format Medium application/pdf
Format Extent 2,247,790 bytes
Identifier ir-main,5388
ARK ark:/87278/s6ff49vg
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 705818
Reference URL https://collections.lib.utah.edu/ark:/87278/s6ff49vg
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