| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Ervin, Kent M. |
| Title |
Hydrogen atom transfer reactions of He+ and Ne+ with H2, D2, and HD |
| Date |
1987 |
| Description |
The hydrogen atom transfer reactions of helium (1 +) and neon(1+) ions with isotopic molecular hydrogen (H2 , D2 , and HD) are investigated using guided ion beam techniques. These reactions are exothermic, but are known to be extremely slow at thermal energies. The cross sections for formation of HeH+ (HeD+) and NeH+ (NeD+) exhibit thresholds at high relative translational energies, 8 to 12 eV c m . Unusual isotope effects are observed in the reaction with HD. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
86 |
| Issue |
11 |
| First Page |
6240 |
| Last Page |
6250 |
| DOI |
10.1063/1.452461 |
| citatation_issn |
219606 |
| Subject |
Transfer reactions; Ion-molecule reactions; Exothermic reactions; Hydrogen; Helium ions; Neon ions; Threshold behavior; Isotope effects |
| Subject LCSH |
Thermochemistry; Excited state chemistry; Surface chemistry; Potential energy surfaces |
| Language |
eng |
| Bibliographic Citation |
Ervin, K. M. & Armentrout, P. B. (1987). Hydrogen atom transfer reactions of He+ and Ne+ with H2, D2, and HD. Journal of Chemical Physics, 86(11), 6240-50. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Ervin, K. M. & Armentrout, P. B., Journal of Chemical Physics, 86(11), 1987 and may be found at http://dx.doi.org/10.1063/1.452461. |
| Format Medium |
application/pdf |
| Format Extent |
1,169,260 bytes |
| Identifier |
ir-main,7079 |
| ARK |
ark:/87278/s6tb1r9x |
| Setname |
ir_uspace |
| ID |
705320 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6tb1r9x |
