Guided ion beam studies of the reaction of Nin+ (n=2-16) with D2: nickel cluster-deuteride bond energies

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Armentrout, Peter B.
Other Author Liu, Fuyi; Liyanage, Rohana
Title Guided ion beam studies of the reaction of Nin+ (n=2-16) with D2: nickel cluster-deuteride bond energies
Date 2002
Description The kinetic-energy dependences of the reactions of Nin+ (n=2-16) with D2 are studied in a guided ion beam tandem mass spectrometer. The products observed are NinD+ for all clusters and NinD2 + for n=5-16. Reactions for formation of NinD+ are observed to exhibit thresholds, whereas cross sections for formation of NinD2+ (n=5-16) exhibit no obvious barriers to reaction.
Type Text
Publisher American Institute of Physics (AIP)
Journal Title The Journal of Chemical Physics
Volume 117
Issue 1
First Page 132
Last Page 141
DOI 10.1063/1.1481855
citatation_issn 219606
Subject Metal clusters; Nickel ions; Bond energies; Deuterides; Collision-induced dissociation; Endothermic reactions
Subject LCSH Thermochemistry; Excited state chemistry; Nickel; Deuterium
Language eng
Bibliographic Citation Liu, F., Liyanage, R., & Armentrout, P. B. (2002). Guided ion beam studies of the reaction of Nin+ (n=2-16) with D2: nickel cluster-deuteride bond energies. Journal of Chemical Physics, 117(1), 132-41.
Rights Management (c)American Institute of Physics. The following article appeared in Liu, F., Liyanage, R., & Armentrout, P. B., Journal of Chemical Physics, 117(1), 2002 and may be found at http://dx.doi.org/10.1063/1.1481855
Format Medium application/pdf
Format Extent 24,158 bytes
Identifier ir-main,8034
ARK ark:/87278/s6df78k9
Setname ir_uspace
ID 705066
Reference URL https://collections.lib.utah.edu/ark:/87278/s6df78k9
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