Translational energy dependence of Ar+ + XY → ArX+ + Y (XY = H2, D2, HD) from thermal to 30 eV c.m.

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Armentrout, Peter B.
Other Author Ervin, Kent M.
Title Translational energy dependence of Ar+ + XY → ArX+ + Y (XY = H2, D2, HD) from thermal to 30 eV c.m.
Date 1985
Description Cross sections for the reactions of Ar+ with H2, D2, and HD to form ArH + and ArD + are measured using a new guided ion beam tandem mass spectrometer which affords an experimental energy range from 0.05 to 500 eV laboratory. The apparatus and experimental techniques are described in detail. Cross sections for H2 and D2 are found to be nearly identical over this entire energy range when compared at the same barycentric energy.
Type Text
Publisher American Institute of Physics (AIP)
Journal Title The Journal of Chemical Physics
Volume 83
Issue 1
First Page 166
Last Page 189
DOI 10.1063/1.449799
citatation_issn 219606
Subject Translational energy; Ion-molecule reactions; Ion energy; Argon; Hydrogen; Endothermic reactions
Subject LCSH Mass spectrometry; Excited state chemistry; Thermochemistry
Language eng
Bibliographic Citation Ervin, K. M. & Armentrout, P. B. (1985). Translational energy dependence of Ar+ + XY → ArX+ + Y (XY = H2, D2, HD) from thermal to 30 eV c.m. Journal of Chemical Physics, 83(1), 166-89.
Rights Management (c)American Institute of Physics. The following article appeared in Ervin, K. M. & Armentrout, P. B., Journal of Chemical Physics, 83(1), 1985 and may be found at http://dx.doi.org/10.1063/1.449799.
Format Medium application/pdf
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Reference URL https://collections.lib.utah.edu/ark:/87278/s6bc4gwc
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