Two-dimensional molecular-based ferrimamagnets incorporating decamethylmetallocenium cations

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Miller, Joel Steven
Other Author Pei, Yu; Turner, Scott S.; Fournes, Leopold; Kahn, Olivier
Title Two-dimensional molecular-based ferrimamagnets incorporating decamethylmetallocenium cations
Date 1996
Description Four new molecular-based magnets have been synthesized, and their magnetic properties have been investigated in detail. Their formulae are [M'(C5Me5)2]2M2[Cu(opba)]3.(DMSO)x(H20)y with M' = Fe, M = Mn, x = 5, y = 4 (1), M' = Fe, M = Co, x = 6, y = 4 (2), M' = Co, M = Mn, x = 5.5, y = 4 (3) and M' = Co, M = Co, x = 5.5, y = 4 (4) [opba = ortfro-phenylenebis (oxamato)]. The decamethylmetallocenium cations [Fe(C5Me5)2]+ and [Co(C5Me5)2]+ are most probably located between the anionic honeycomb-like networks Mn2[Cu(opba)]3 and Co2[Cu(opba)]3.
Type Text
Publisher Royal Society of Chemistry
Volume 6
Issue 9
First Page 1521
Last Page 1525
Subject Magnetic; Compounds
Language eng
Bibliographic Citation Pei, Y.,Turner, S. S., Fournes, L., Miller, J. S., & Kahn, O. (1996). Two-dimensional molecular-based ferrimamagnets incorporating decamethylmetallocenium cations. Journal of Materials Chemistry, 6(9), 1521-5.
Rights Management (c)Royal Society of Chemistry
Format Medium application/pdf
Format Extent 3,711,369 bytes
Identifier ir-main,5624
ARK ark:/87278/s6kp8kg1
Setname ir_uspace
ID 704376
Reference URL https://collections.lib.utah.edu/ark:/87278/s6kp8kg1
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