The 3d?Ni(?F)3d10Cu???*? manifold of excited electronic states of NiCu

Update item information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Spain, Eileen M.
Title The 3d?Ni(?F)3d10Cu???*? manifold of excited electronic states of NiCu
Date 1992
Description Diatomic NiCu has been supersonically cooled in a molecular beam and investigated by resonant two-photon ionization spectroscopy. A total of nine band systems connecting the ground 3d?Ni3??Cu??, X 2?5/2 state to the 3d?Ni(3F)3d??Cu??*?? manifold of states have been found, and bands of eight of these systems have been rotationally resolved and analyzed. Land S-uncoupling interactions have been found between two pairs of states, resulting in B[11.9]2.5 ~C[1.91]1.5 and [10.4]2.5~[10.4]1.5(?) heterogeneous perturbations. In the case of the B-C interaction, the magnitude of the perturbation matrix element has been deduced. The detailed spectroscopic analysis of the 3d?Ni(3F)3d??Cu??*?? manifold of states presented in this paper allows the electronic structure of NiCu to be understood in depth and provides a database for comparison to the ligand-field plus spin-orbit calculation of the NiCu excited states presented in the following paper.
Type Text
Publisher American Institute of Physics (AIP)
Volume 97
Issue 7
First Page 4633
Last Page 4640
DOI 10.1063/1.463866
Language eng
Bibliographic Citation Spain, E. M., & Morse, M. D. (1992). The 3d?Ni(?F)3d10Cu???*? manifold of excited electronic states of NiCu. Journal of Chemical Physics, 97(7), 4633-40.
Rights Management ¬©American Institute of Physics. The following article appeared in Spain, E. M., & Morse, M. D. (1992). The 3d?Ni(?F)3d10Cu???*? manifold of excited electronic states of NiCu. Journal of Chemical Physics, 97(7), 4633-40. and may be found at http://dx.doi.org/10.1063/1.463866.
Format Medium application/pdf
Format Extent 1,051,683 bytes
Identifier ir-main,16997
ARK ark:/87278/s6cc1hxd
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 704133
Reference URL https://collections.lib.utah.edu/ark:/87278/s6cc1hxd
Back to Search Results