Oxidation reactions at variably sized transition metal centers: Fen+ and Nbn+ + O2 (N=1-3)

Update item information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Armentrout, Peter B.
Other Author Loh, S. K.; Lian, Li
Title Oxidation reactions at variably sized transition metal centers: Fen+ and Nbn+ + O2 (N=1-3)
Date 1989
Description Cross sections for the reactions of Fen+ and Nbn+ (n = 1-3) with 02 are measured as a function of kinetic energy over a range of 0 to > 10 eV. In all systems, analysis yields insight into the kinetics and thermochemistry of the oxidation processes. Nbn+ reaction with 02 exothermically near the Langevin-Gioumousis-Stevenson close-collision limit, driven by formation of strong NbO+ and NbO bonds. Fen+ are less reactive, although oxidation becomes progressively more facile as the size of the reactant increases from Fe+ to Fe3+ .
Type Text
Publisher American Institute of Physics (AIP)
Journal Title The Journal of Chemical Physics
Volume 91
Issue 10
First Page 6148
Last Page 6163
DOI 10.1063/1.457434
citatation_issn 219606
Subject Metal clusters; Nobium ions; Iron ions; Exothermic reactions
Subject LCSH Surface chemistry; Transition metal ions; Oxidation; Thermochemistry
Language eng
Bibliographic Citation Loh, S. K., Lian, L., & Armentrout, P. B. (1989). Oxidation reactions at variably sized transition metal centers: Fen+ and Nbn+ + O2 (N=1-3). Journal of Chemical Physics, 91(10), 6148-63.
Rights Management (c)American Institute of Physics. The following article appeared in Loh, S. K., Lian, L., & Armentrout, P. B., Journal of Chemical Physics, 91(10), 1989 and may be found at http://dx.doi.org/10.1063/1.457434.
Format Medium application/pdf
Format Extent 1,858,722 bytes
Identifier ir-main,7370
ARK ark:/87278/s6zg79h4
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 704082
Reference URL https://collections.lib.utah.edu/ark:/87278/s6zg79h4
Back to Search Results