Spectroscopy and electronic structure of jet-cooled NiCu

Update item information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Fu, Zhenwen
Title Spectroscopy and electronic structure of jet-cooled NiCu
Date 1988
Description Diatomic nickel-copper, NiCu, has been investigated by resonant two-photon ionization spectroscopy in a jet-cooled molecular beam. Six band systems have been identified over the range 11 500-16 500 cm-1. The ground state of NiCu has been determined to be X 2?5/2, with ?"e = 273.01 ? 1.15 cm-1, ?"exe" = 1.00 ? 0.38 cm-1, and r"e = 2.233 ? 0.006 ?. This state derives from a strongly bound (2.05 ? 0.10 eV) 3d10Cu3d9Ni4s?2 configuration. Excited states observed in this work derive from the more weakly bound 3d10Cu3d8Ni4s?24s?*1 configuration, and are characterized by smaller vibrational frequencies (191-208 cm-1) and a longer bond length (2.351 ? 0.005 ?) than the ground X2?5/2 state.
Type Text
Publisher American Institute of Physics (AIP)
Volume 90
Issue 7
First Page 3417
Last Page 3426
DOI 10.1063/1.455850
Language eng
Bibliographic Citation Fu, Z., & Morse, M. D. (1988). Spectroscopy and electronic structure of jet-cooled NiCu. Journal of Chemical Physics, 90(7), 3417-26.
Rights Management ¬©American Institute of Physics. The following article appeared in Fu, Z., & Morse, M. D. (1988). Spectroscopy and electronic structure of jet-cooled NiCu. Journal of Chemical Physics, 90(7), 3417-26. and may be found at http://dx.doi.org/10.1063/1.455850.
Format Medium application/pdf
Format Extent 1,062,608 bytes
Identifier ir-main,16971
ARK ark:/87278/s6v98s9z
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 703582
Reference URL https://collections.lib.utah.edu/ark:/87278/s6v98s9z
Back to Search Results