Spin-orbit state-selected reactions of Xe+(2P3/2 and 2P1/2) with H2, D2, and HD

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Armentrout, Peter B.
Other Author Ervin, Kent M.
Title Spin-orbit state-selected reactions of Xe+(2P3/2 and 2P1/2) with H2, D2, and HD
Date 1989
Description Spin-orbit state-selected reactions of X e + (2Pj ), j = 3/2 and 1/2, with isotopic molecular hydrogen (H2 , D2 , and HD) to form X e H + and XeD + are studied using guided ion beam mass spectrometry. Reaction cross sections are determined as a function of reactant kinetic energy from near thermal energy to 15 eV c m . Although the reaction of Xe + ( 2p 1/2 ) + H2 to form ground state products XeH+ + H is exothermic, no reaction is observed at low energies and the reaction cross section is zero or small at higher energies.
Type Text
Publisher American Institute of Physics (AIP)
Journal Title The Journal of Chemical Physics
Volume 90
Issue 1
First Page 118
Last Page 126
DOI 10.1063/1.456516
citatation_issn 219606
Subject Spin-orbit; Xenon ions; Hydrogen isotopes; Isotope effects; Ion-molecule reactions
Subject LCSH Thermochemistry; Excited state chemistry; Surface chemistry; Potential energy surfaces
Language eng
Bibliographic Citation Ervin, K. M. & Armentrout, P. B. (1989). Spin-orbit state-selected reactions of Xe+(2P3/2 and 2P1/2) with H2, D2, and HD. Journal of Chemical Physics, 90(1), 118-26.
Rights Management (c)American Institute of Physics. The following article appeared in Ervin, K. M. & Armentrout, P. B., Journal of Chemical Physics, 90(1) 1989 and may be found at http://dx.doi.org/10.1063/1.456516.
Format Medium application/pdf
Format Extent 940,543 bytes
Identifier ir-main,7083
ARK ark:/87278/s62r48vr
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 703415
Reference URL https://collections.lib.utah.edu/ark:/87278/s62r48vr
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