Spectroscopy of mixed early-late transition metal diatomics: ScNi, YPd, and ZrCo

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Arrington, Caleb A.; Doverstal, Mats
Title Spectroscopy of mixed early-late transition metal diatomics: ScNi, YPd, and ZrCo
Date 1994
Description Resonant two-photon ionization spectroscopy has been employed to investigate the spectra of the jet-cooled transition metal diatomics ScNi, YPd, and ZrCo, which are isovalent species which possess ~or are thought to possess! an X 2?+ ground state. Several electronic band systems have been observed for these species in the near infrared, and the analysis of these systems is reported. Ground state vibrational intervals of ?G"1/2=334.5 ? 1.0, 264.4?0.2, and 357.7 cm-1 have been determined for ScNi, YPd, and ZrCo, respectively. The spectroscopic results obtained for ScNi and YPd are compared to theoretical calculations performed by other researchers, and a discussion of the chemical bonding in these species is presented.
Type Text
Publisher American Institute of Physics (AIP)
Volume 102
Issue 5
First Page 1895
Last Page 1904
DOI 10.1063/1.468755
Language eng
Bibliographic Citation Arrington, C. A., Morse, M. D., & Doverstal, M. (1994). Spectroscopy of mixed early-late transition metal diatomics: ScNi, YPd, and ZrCo. Journal of Chemical Physics, 102(5), 1895-904.
Rights Management ©American Institute of Physics. The following article appeared in Arrington, C. A., Morse, M. D., & Doverstal, M. (1994). Spectroscopy of mixed early-late transition metal diatomics: ScNi, YPd, and ZrCo. Journal of Chemical Physics, 102(5), 1895-904. and may be found at doi:10.1063/1.468755.
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Format Extent 167,835 bytes
Identifier ir-main,16950
ARK ark:/87278/s6571w69
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 703100
Reference URL https://collections.lib.utah.edu/ark:/87278/s6571w69
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